34599-72-9

Basic information

• Product Name: methyl 2-(prop-1-en-1-yl)benzoate
• CAS NO: 34599-72-9
• Molecular Weight: 176.215
• Mol File: 34599-72-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 2-(prop-1-en-1-yl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(prop-1-en-1-yl)benzoate(34599-72-9)
• EPA Substance Registry System: methyl 2-(prop-1-en-1-yl)benzoate(34599-72-9)

Safety Data

• Hazardous Substances Data: 34599-72-9(Hazardous Substances Data)

Upstream product

• 4122-56-9 methyl o-formylbenzoate 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 61463-59-0 2-allyl benzoic acid methyl ester 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 201230-82-2 carbon monoxide 
• 17763-70-1 methyl 2-(trifluoromethylsulfonyloxy)benzoate 
• 24850-33-7 allyltributylstanane 
• 119-67-5 o-carboxybenzaldehyde 

Downstream Products

• 68692-74-0 2-[(1Z)-prop-1-en-1-yl]benzoic acid 
• 68692-74-0 (E)-2-(prop-1-en-1-yl)benzoic acid 
• 90843-22-4 2-(prop-1-en-1-yl)benzoic acid 

Relevant articles and documents

Ni-Catalyzed Alkene Carboacylation via Amide C-N Bond Activation

We report Ni-catalyzed formal carboacylation of o-allylbenzamides with arylboronic acid pinacol esters. The reaction is triggered by oxidative addition of an activated amide C-N bond to a Ni(0) catalyst and proceeds via alkene insertion into a Ni(II)-acyl bond. The exo-selective carboacylation reaction generates 2-benzyl-2,3-dihydro-1H-inden-1-ones in moderate to high yields (46-99%) from a variety of arylboronic acid pinacol esters and substituted o-allylbenzamides. These results show that amides are practical substrates for alkene carboacylation via amide C-N bond activation, and this approach bypasses challenges associated with alkene carboacylation triggered by C-C bond activation.

Selenium-mediated synthesis of biaryls through rearrangement

"Chemical Equation Presented" A new cyclization of β-keto ester substituted stilbene derivatives using selenium electrophiles in the presence of Lewis acids is described. Substituted naphthols are obtained through cyclization and subsequent 1,2-rearrangement of aryl groups under very mild reaction conditions.