34938-47-1Relevant articles and documents
Properties and applications of designable and photo/redox dual responsive surfactants with the new head group 2-arylazo-imidazolium
Lin, Changxu,Yang, Long,Xu, Mengchun,An, Qi,Xiang, Zheng,Liu, Xiangyang
, p. 51552 - 51561 (2016)
2-Arylazo-imidazolium was investigated as a new hydrophilic head group for ionic liquid surfactants. With the azo moiety at the 2-C site of imidazolium, it was designed to expand the extensibility of the functionalization and controllability of assembly. Structural designability was displayed by the colloidal chemical properties like surface tension, conductivity and steady fluorescence quenching of the designed surfactants. Their corresponding responsiveness towards photo stimuli was compared. Further properties like the reversible electrochemical redox responsiveness and the instinctive fluorescence of the designed surfactants were discovered. A potential application was demonstrated by the photo-controllable fabrication of Au nanostars.
Influence of the cavity size of cyclodextrins on the photochromism of azoimidazoles
Gayen, Pallab,Karmakar, Abhisake,Sepay, Nayim,Sinha, Chittaranjan
, (2021/12/20)
1-Alkyl-2-(arylazo)imidazole (RaaiR/) exists in trans configuration about the –N[dbnd]N- bond. Upon optical excitation in UV region the trans-configuration isomerises to cis-RaaiR/. The photochromism is very susceptible to internal substituents and external environment like solvent polarity, viscosity and presence of innocent foreign species. In this work, the trans-to-cis photoisomerisation of RaaiR/has been studied in DMF solution of cyclodextrin (α/β/γ-CD). The rate of trans-to-cis isomerisation is decreased in presence of CD compared to native form of RaaiR/. The quantum yield of the photoisomerisation is decreased by 35–55% in inclusion phase, CD@RaaiR/, than free photochrome and follows the rate sequence: free state > γ-cyclodextrin > β-cyclodextrin > α-cyclodextrin. The cis-to-trans isomerisation proceeds slowly in visible light irradiation while it is appreciably fast with increasing temperature. The activation energy (Ea) of cis → trans thermal isomerisation is also diminished compared to free state of photochrome. The absorption spectral studies have been used in case of Pai-C18H37 with β-CD and inclusion constant is Kb ?= ?0. 121 M?1. The 1H NMR spectral measurement also suggests interaction of aryl protons with cavity protons of β-CD. DFT computation is also attempted to examine the inclusion of RaaiR/with CD and the negative values of binding energy show that the process of inclusion is spontaneous and complexes formed are stable.
A facile and new approach to synthesize 2-amino-4-(4-amoinophenyl)-1H-1,3- diazol-1-yl-alkylaminomethanethiones
Verma, Raman K.,Aggarwal, Monika,Bansal, Manisha,Kaur, Inder Preet
, p. 483 - 491 (2008/04/01)
An "intellectual connection" approach to design a facile and new synthesis of suitably substituted 2-aminoimidazole-based precursors of expected anti-asthmatic agents through a benzidine type of rearrangement of 2-phenylazoimidazole and subsequent coupling of the product thus obtained with alkylisothiocyanates involving a degenerative operation, thereby improving the time frame of the overall synthetic sequence, is reported. The alkylisothiocyanates required in this synthetic sequence are prepared using a best combination of reported methods. The compounds reported here can be used to produce derivatives of other biological agents. Birkhaeuser 2007.