862702-75-8

Basic information

• Product Name: [(η5-cyclopentadienyl)Ru(PPh3)(2-(phenylazo)imidazole)][PF6]
• CAS NO: 862702-75-8
• Molecular Weight: 745.609
• Mol File: 862702-75-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(η5-cyclopentadienyl)Ru(PPh3)(2-(phenylazo)imidazole)][PF6](CAS DataBase Reference)
• NIST Chemistry Reference: [(η5-cyclopentadienyl)Ru(PPh3)(2-(phenylazo)imidazole)][PF6](862702-75-8)
• EPA Substance Registry System: [(η5-cyclopentadienyl)Ru(PPh3)(2-(phenylazo)imidazole)][PF6](862702-75-8)

Safety Data

• Hazardous Substances Data: 862702-75-8(Hazardous Substances Data)

Upstream product

• 32993-05-8 chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) 
• 34938-47-1 2-(phenyldiazenyl)imidazole 

Relevant articles and documents

Syntheses and characterization of η5-cyclopentadienyl and η5-indenyl ruthenium(II) complexes of arylazoimidazoles: The molecular structure of the complex [(η5-C5H 5)Ru(PPh3)(C6H5-NN-C 3H3N2)]+

The complex [(η5-C5H5)Ru(PPh 3)2Cl] (1) reacts with several arylazoimidazole (RaaiR′) ligands, viz., 2-(phenylazo)imidazole (Phai-H), 1-methyl-2-(phenylazo)imidazole (Phai-Me), 1-ethyl-2-(phenylazo)imidazole (Phai-Et), 2-(tolylazo)imidazole (Tai-H), 1-methyl-2-(tolylazo)imidazole (Tai-Me) and 1-ethyl-2-(tolylazo)imidazole (Tai-Et), gave complexes of the type [(η5-C5H5)Ru(PPh3)(RaaiR′) ]+ {where R, R′ = H (2), R = H, R′ = CH3 (3), R = H, R′ = C2H5 (4), R = CH3, R′ = H (5), R, R′ = CH3 (6), R = CH3, R′ = C 2H5 (7)}. The complex [(η5-C 9H7)Ru(PPh3)2(CH3CN)] + (8) undergoes reactions with a series of N,N-donor azo ligands in methanol yielding complexes of the type [(η5-C9H 7) Ru(PPh3)(RaaiR′)]+ {where R, R′ = H (9), R = H, R′ = CH3 (10), R = CH3, R′ = H (11), R = CH3, R′ = C2H5 (12)}, respectively. These complexes were characterized by FT IR and FT NMR spectroscopy as well as by analytical data. The molecular structure of the complex [(η5-C5H5)Ru(PPh 3)(C6H5-NN-C3H3N 2)]+ (2) was established by single crystal X-ray diffraction study.