34954-40-0

Basic information

• Product Name: Benzenesulfonamide, 4-methoxy-N-2-propenyl-
• CAS NO: 34954-40-0
• Molecular Formula: C10H13NO3S
• Molecular Weight: 227.284
• Mol File: 34954-40-0.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, 4-methoxy-N-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, 4-methoxy-N-2-propenyl-(34954-40-0)
• EPA Substance Registry System: Benzenesulfonamide, 4-methoxy-N-2-propenyl-(34954-40-0)

Safety Data

• Hazardous Substances Data: 34954-40-0(Hazardous Substances Data)

Upstream product

• 98-68-0 4-methoxy-phenyl-sulphonyl chloride 
• 1129-26-6 4-methoxybenzene sulfonamide 
• 107-18-6 allyl alcohol 
• 4547-64-2 4-methoxybenzenesulfonyl azide 
• 76-63-1 allytriphenyltin 
• 24850-33-7 allyltributylstanane 
• 107-11-9 1-amino-2-propene 

Downstream Products

• 946076-62-6 ethyl 4-ethoxythiocarbonylsulfanyl-5-(4-methoxybenzenesulfonylamino)pentanoate 
• 946076-27-3 N-allyl-N-((4-methoxyphenyl)sulfonyl)acetamide 
• 1236041-06-7 C₁₁H₁₅NO₄S 
• 35088-86-9 4-methoxyl-N-propylbenzenesulfonamide 
• 1613288-05-3 (S)-4-methoxy-N-(2-methyl-3-oxopropyl)benzenesulfonamide 
• 1613288-09-7 C₁₁H₁₅NO₄S 
• 1259403-93-4 N-allyl-4-methoxy-N-(phenylethynyl)benzenesulfonamide 
• 1433140-31-8 3-(4-methoxyphenylsulfonyl)-1-phenyl-3-aza-bicyclo[3.1.0]hexan-2-one 
• 1352227-51-0 C₂₁H₂₃NO₅S 
• 18836-84-5 1-[(4-methoxyphenyl)sulfonyl]-1H-pyrrole 

Relevant articles and documents

Twofold Radical-Based Synthesis of N, C-Difunctionalized Bicyclo[1.1.1]pentanes

Bicyclo[1.1.1]pentylamines (BCPAs) are of growing importance to the pharmaceutical industry as sp3-rich bioisosteres of anilines and N-tert-butyl groups. Here we report a facile synthesis of 1,3-disubstituted BCPAs using a twofold radical functionalization strategy. Sulfonamidyl radicals, generated through fragmentation of α-iodoaziridines, undergo initial addition to [1.1.1]propellane to afford iodo-BCPAs; the newly formed C-I bond in these products is then functionalized via a silyl-mediated Giese reaction. This chemistry also translates smoothly to 1,3-disubstituted iodo-BCPs. A wide variety of radical acceptors and iodo-BCPAs are accommodated, providing straightforward access to an array of valuable aniline-like isosteres.

Visible-Light-Mediated Annulation of Electron-Rich Alkenes and Nitrogen-Centered Radicals from N-Sulfonylallylamines: Construction of Chloromethylated Pyrrolidine Derivatives

A visible-light-mediated annulation of N-sulfonylallylamines and olefins is reported. Rapid access to highly functionalized chloromethylated pyrrolidines can be achieved using mild conditions for the generation of nitrogen-centered radicals. Both a transi

Copper-catalyzed trifluoromethylation and cyclization of aromatic-sulfonyl-group-tethered alkenes for the construction of 1,2-benzothiazinane dioxide type compounds

A multi-talented system: An efficient copper-catalyzed tandem trifluoromethylation/annulation of an electron-deficient aromatic ring has been developed. This method provides a powerful and straightforward way to synthesize trifluoromethylated 1,2-benzothiazinane dioxides under mild conditions (see scheme). The mechanism was investigated by a series of kinetic experiments and isotopic labeling studies.