35010-10-7

Basic information

• Product Name: 1-(2-nitrophenyl)-2-phenylethane-1,2-dione
• Synonyms: 1-(2-nitrophenyl)-2-phenylethane-1,2-dione
• CAS NO: 35010-10-7
• Molecular Weight: 255.23
• Mol File: 35010-10-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-(2-nitrophenyl)-2-phenylethane-1,2-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-nitrophenyl)-2-phenylethane-1,2-dione(35010-10-7)
• EPA Substance Registry System: 1-(2-nitrophenyl)-2-phenylethane-1,2-dione(35010-10-7)

Safety Data

• Hazardous Substances Data: 35010-10-7(Hazardous Substances Data)

Upstream product

• 35010-17-4 1-nitro-2-phenylethynyl-benzene 
• 64-19-7 acetic acid 
• 451-40-1 phenyl benzyl ketone 
• 71-43-2 benzene 
• 22751-23-1 (2-nitrophenyl)acetyl chloride 
• 610-14-0 2-nitrobenzyl chloride 
• 552-89-6 2-nitro-benzaldehyde 
• 1449-46-3 benzyltriphenylphosphonium bromide 
• 4714-25-4 2-nitrostilbene 
• 4264-29-3 (E)-2-nitrostilbene 
• 108-24-7 acetic anhydride 
• 4212-33-3 2-(2-nitrophenyl)-1-phenylethanone 
• 7697-37-2 nitric acid 
• 53774-34-8 2-(2-nitrophenyl)-3-phenyloxirane 

Downstream Products

• 552-16-9 ortho-nitrobenzoic acid 
• 65-85-0 benzoic acid 
• 133253-56-2 2,2'-dinitrobenzil 
• 871881-07-1 2,3'-dinitro-benzil 
• 1969-74-0 2-phenylisatogen 

Relevant articles and documents

Synthesis of α-diketones from alkylaryl- and diarylalkynes using mercuric salts

Both alkylarylalkynes and diarylalkynes 1 are converted into the α-diketones 2 in good yield by the use of mercuric salts, e.g., mercuric nitrate hydrate or mercuric triflate, in the presence of water. Other mercuric salts, e.g., sulfate, chloride, acetate, or trifluoroacetate, do not provide the diketone product. A possible mechanism is proposed.

Mild oxidation of diarylacetylenes to 1,2-diketones using oxone in trifluoroacetic acid

A variety of 1,2-diaryldiketones were synthesized in 15-90% yields by treatment of diarylacetylenes with Oxone as the oxidant in trifluoroacetic acid. Oxidation of 1-nitro-2-(phenylethynyl) benzene and 2,4￠-(ethyne-1,2-diyl) bis(nitrobenzene) furnished 1-benzoylbenzo[c]isoxazol-3(1H)-one and benzo[c]isoxazol-3-yl(4-nitrophenyl)methanone as the major products, respectively. Georg Thieme Verlag Stuttgart.

A new general approach for the synthesis of 2-substituted-3H-indol-3-one N-oxide derivatives

2-aryl (phenyl, 1,3-benzodioxolyl) and 2-alkyl (ethyl, sec-butyl)-3H-indol-3-one N-oxides were synthesized by a new general method involving a reductive intramolecular cyclization reaction of ortho-diketo nitrobenzene derivatives.