3516-73-2

Basic information

• Product Name: 2-Chlor-benzoyl-malonsaeure-diethylester
• Synonyms: 2-Chlor-benzoyl-malonsaeure-diethylester
• CAS NO: 3516-73-2
• Molecular Weight: 298.723
• Mol File: 3516-73-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Chlor-benzoyl-malonsaeure-diethylester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Chlor-benzoyl-malonsaeure-diethylester(3516-73-2)
• EPA Substance Registry System: 2-Chlor-benzoyl-malonsaeure-diethylester(3516-73-2)

Safety Data

• Hazardous Substances Data: 3516-73-2(Hazardous Substances Data)

Upstream product

• 609-65-4 o-chlorobenzoyl chloride 
• 105-53-3 diethyl malonate 
• 118-91-2 ortho-chlorobenzoic acid 

Downstream Products

• 289706-53-2 ethyl (2'-chlorophenyl)-3-oxo-2-(N-ethylamino)methylene propionate 
• 60868-43-1 2-(2-chlorobenzoyl)-3-ethoxyacrylic acid ethyl ester 
• 19112-35-7 ethyl (2-chlorobenzoyl)acetate 

Relevant articles and documents

Zinc-mediated alkylation and acylation of 1,3-dicarbonyl compounds

1,3-Dicarbonyl compounds undergo smooth allylation, benzylation, propargylation, and acylation with halides using metallic zinc in DMF at 60 °C to afford the corresponding allyl, benzyl, 2-propynyl, and acylated 1,3-diesters in good yields. In the case of cyclic 1,3-diketones, the corresponding enol ethers are obtained as sole products instead of C-alkylation.