35288-49-4

Basic information

• Product Name: 1 4-PHENYLENEDIACRYLOYL CHLORIDE TECH
• Synonyms: 3,3'-Benzene-1,4-diylbisprop-2-enoylchloride;1 4-PHENYLENEDIACRYLOYL CHLORIDE TECH
• CAS NO: 35288-49-4
• Molecular Formula: C₁₂H₈Cl₂O₂
• Molecular Weight: 255.09672
• Product Categories: Reagents for Polymerization;Biomaterials;Crosslinkers;Crosslinking Agents;Materials Science;Polymer Science;Biocompatible/Biodegradable Materials;CrosslinkersMaterials Science;Crosslinking Agents;Polymer Additives;Polymer Science
• Mol File: 35288-49-4.mol
• Article Data: 4

Chemical Properties

• Melting Point: >300 °C (dec.)(lit.)
• Appearance: /
• Storage Temp.: 2-8°C
• Sensitive: Moisture Sensitive
• CAS DataBase Reference: 1 4-PHENYLENEDIACRYLOYL CHLORIDE TECH(CAS DataBase Reference)
• NIST Chemistry Reference: 1 4-PHENYLENEDIACRYLOYL CHLORIDE TECH(35288-49-4)
• EPA Substance Registry System: 1 4-PHENYLENEDIACRYLOYL CHLORIDE TECH(35288-49-4)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 1759 8/PG 3
• WGK Germany: 3
• HazardClass: 8
• Hazardous Substances Data: 35288-49-4(Hazardous Substances Data)

Usage

Description

1,4-Phenylenediacryloyl Chloride TECH, also known as diacryloyl chloride compound, is a chemical compound utilized in the production of polymers and resins. It contains two acryloyl chloride functional groups, which play a crucial role in the formation of polymers through crosslinking reactions. 1 4-PHENYLENEDIACRYLOYL CHLORIDE TECH is particularly valuable in the creation of high-performance materials such as adhesives, coatings, and composites. Furthermore, it serves as a monomer in the synthesis of polymers with unique properties, making it a versatile and significant compound in the chemical industry.

Uses

Used in Polymer and Resin Production:
1,4-Phenylenediacryloyl Chloride TECH is used as a monomer for the production of polymers and resins. Its acryloyl chloride functional groups facilitate crosslinking reactions, resulting in the formation of high-performance materials.
Used in Adhesives Industry:
1,4-Phenylenediacryloyl Chloride TECH is used as a key component in the formulation of adhesives. 1 4-PHENYLENEDIACRYLOYL CHLORIDE TECH's ability to form crosslinked polymers contributes to the development of strong and durable adhesives for various applications.
Used in Coatings Industry:
1,4-Phenylenediacryloyl Chloride TECH is used as a monomer in the synthesis of polymers for coatings. The resulting polymers provide enhanced properties such as durability, resistance to chemicals, and UV protection, making them suitable for various coating applications.
Used in Composites Industry:
1,4-Phenylenediacryloyl Chloride TECH is used as a monomer in the production of polymers for composite materials. The crosslinked polymers formed from this compound contribute to the development of high-strength and lightweight composites, which are essential in various industrial applications.
Used in Synthesis of Special Polymers:
1,4-Phenylenediacryloyl Chloride TECH is used as a monomer in the synthesis of polymers with special properties. These polymers can be tailored for specific applications, making this compound an important component in the chemical industry.

Upstream product

• 16323-43-6 1,4-phenylenediacrylic acid 
• 623-27-8 terephthalaldehyde, 

Downstream Products

• 34042-66-5 p-Phenylendiacrylsaeure-bis-dimethylhydrazid 
• 131814-55-6 1,4-di(β-propenoyloxyisoflavonyl-7)benzene 
• 495-52-3 s-hydrindacene 
• 4251-21-2 3,3'-(1,4-phenylene)dipropanoic acid 
• 14927-64-1 3,5,6,7-tetrahydro-2H-s-indacen-1-one 
• 14927-65-2 3,6,7,8-tetrahydro-2H-as-indacen-1-one 
• 5312-03-8 dimethyl 3,3'-(1,4-phenylene)dipropanoate 
• 23291-98-7 3-(2.3-Dihydro-1H-inden-5-yl)-propanoic acid 
• 19417-58-4 [1,4-phenylene]-bis(3-hydroxypropane) 
• 19417-59-5 1,4-bis-(3-bromopropyl)-benzene 
• 137334-85-1 1,4-bis<4-(chloroformyl)-4-methylpentyl>benzene 
• 137334-84-0 1,4-bis(4-carboxy-4-methylpentyl)benzene 
• 137334-87-3 1,4-bis<4,4-dimethyl-5-(ethoxycarbonyl)pentyl>benzene 
• 137334-86-2 1,4-bis(6-diazo-4,4-dimethyl-5-oxohexyl)benzene 

Relevant articles and documents

The Cooperative Effect of Both Molecular and Supramolecular Chirality on Cell Adhesion

Although helical nanofibrous structures have great influence on cell adhesion, the role played by chiral molecules in these structures on cells behavior has usually been ignored. The chirality of helical nanofibers is inverted by the odd–even effect of methylene units from homochiral l-phenylalanine derivative during assembly. An increase in cell adhesion on left-handed nanofibers and weak influence of cell behaviors on right-handed nanofibers are observed, even though both were derived from l-phenylalanine derivatives. Weak and negative influences on cell behavior was also observed for left- and right-handed nanofibers derived from d-phenylalanine, respectively. The effect on cell adhesion of single chiral molecules and helical nanofibers may be mutually offset.

Cyclization of propargylic amides: Mild access to oxazole derivatives

The substrate scope, the mechanistic aspects of the gold-catalyzed oxazole synthesis, and substrates with different aliphatic, aromatic, and functional groups in the side chain were investigated. Even molecules with several propargyl amide groups could easily be converted, delivering di- and trioxazoles with interesting optical properties. Furthermore, the scope of the gold(I)-catalyzed alkylidene synthesis was investigated. Further functionalizations of these isolable intermediates of the oxazole synthesis were developed and chelate ligands can be obtained. The use of Barluenga's reagent offers a new and mild access to the synthetically valuable iodoalkylideneoxazoles from propargylic amides, this reagent being superior to other sources of halogens.