353264-99-0

Basic information

• Product Name: Benzenesulfonamide, 4-methyl-N-(2-methylpropylidene)-
• CAS NO: 353264-99-0
• Molecular Formula: C11H15NO2S
• Molecular Weight: 225.312
• Mol File: 353264-99-0.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, 4-methyl-N-(2-methylpropylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, 4-methyl-N-(2-methylpropylidene)-(353264-99-0)
• EPA Substance Registry System: Benzenesulfonamide, 4-methyl-N-(2-methylpropylidene)-(353264-99-0)

Safety Data

• Hazardous Substances Data: 353264-99-0(Hazardous Substances Data)

Upstream product

• 70-55-3 toluene-4-sulfonamide 
• 78-84-2 isobutyraldehyde 
• 6873-55-8 p-tolylsulfinyl amide 
• 1323310-69-5 N-(2-methyl-1-(phenylsulfonyl)propyl)-p-toluenesulfonamide 

Downstream Products

• 902774-03-2 N-[1-(1H-indol-3-yl)-2-methyl-propyl]-4-methyl-benzenesulfonamide 
• 102-54-5 ferrocene 
• 1006605-88-4 (C₅H₅)Fe((CH₃)3SiC₅H₃CH(CH(CH₃)2)NHSO₂C₆H₄CH₃) 
• 1006866-74-5 (C₅H₅)Fe(C₆H₅CH(OH)C₅H₃CH(CH(CH₃)2)NHSO₂C₆H₄CH₃) 
• 1006605-91-9 (C₅H₅)Fe((C₆H₅)2C(OH)C₅H₃CH(CH(CH₃)2)NHSO₂C₆H₄CH₃) 
• 1006605-87-3 (C₅H₅)Fe(C₆H₅SC₅H₃CH(CH(CH₃)2)NHSO₂C₆H₄CH₃) 
• 1006605-89-5 (C₅H₅)Fe((C₄H₉)3SnC₅H₃CH(CH(CH₃)2)NHSO₂C₆H₄CH₃) 
• 1064197-27-8 [1R,S(R)]-N-[2-methyl-1-(2-tert-butylsulfinylphenyl)-propyl]-4-methylbenzenesulfonamide 

Relevant articles and documents

Alkenyl Exchange of Allylamines via Nickel(0)-Catalyzed C-C Bond Cleavage

A functional group exchange reaction between allylamines and alkenes via nickel-catalyzed C - C bond cleavage and formation was developed. This reaction provides a novel protocol, which does not require the use of unstable imine substrates, for the synthesis of allylamines, which are widely used in the production of fine chemicals, pharmaceuticals, and agrochemicals.

Nickel(0)-Catalyzed Hydroalkenylation of Imines with Styrene and Its Derivatives

A nickel(0)-catalyzed hydroalkenylation of imines with styrene and its derivatives is described. A wide range of aromatic and aliphatic imines directly coupled with styrene and its derivatives, thus providing various synthetically useful allylic amines with up to 95 % yield. The reaction offers a new atom- and step-economical approach to allylic amines by using alkenes instead of alkenyl-metallic reagents. Experiments and DFT calculations showed that TsNH2 promotes the proton transfer from the coordinated olefin to the imine, accompanied by a new C?C bond formation.

Reduction of sulfonylimines with raney nickel

Raney-Ni/EtOH reduction of different N-sulfonylimines provides a new entry for synthesizing sulfonamides in good yields under mild conditions. This protocol, which does not require additional hydrogen, constitutes a cheap, safe, and easy-to-handle alterna