35454-01-4

Basic information

• Product Name: benzyl amino(oxo)acetate
• CAS NO: 35454-01-4
• Molecular Formula: C₉H₉NO₃
• Molecular Weight: 179.1727
• Mol File: 35454-01-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 320.6°C at 760 mmHg
• Flash Point: 169.2°C
• Density: 1.252g/cm³
• Vapor Pressure: 0.000315mmHg at 25°C
• Refractive Index: 1.553
• CAS DataBase Reference: benzyl amino(oxo)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl amino(oxo)acetate(35454-01-4)
• EPA Substance Registry System: benzyl amino(oxo)acetate(35454-01-4)

Safety Data

• Hazardous Substances Data: 35454-01-4(Hazardous Substances Data)

Upstream product

• 7579-36-4 dibenzyl oxalate 
• 35249-73-1 benzyl chlorooxalate 
• 100-51-6 benzyl alcohol 
• 52267-51-3 benzyl diazoacetate 

Relevant articles and documents

Oxidative Coupling of Diazo and NH4I: A Route to Primary Oxamates and α-Ketoamides

A simple and efficient method has been developed for the preparation of primary oxamates and α-ketoamides through the oxidative coupling of diazo compounds and NH4I. Under the optimized reaction conditions, a range of diazoesters and α-diazoketones was explored, and the corresponding products were obtained in moderate to good yields. This protocol is metal-free, is performed under mild conditions, has a wide substrate scope, and offers operational simplicity.