35717-21-6

Basic information

• Product Name: 2-chloro-4-phenylthiophene
• Synonyms: 2-chloro-4-phenylthiophene
• CAS NO: 35717-21-6
• Molecular Weight: 194.685
• Mol File: 35717-21-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 2-chloro-4-phenylthiophene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-4-phenylthiophene(35717-21-6)
• EPA Substance Registry System: 2-chloro-4-phenylthiophene(35717-21-6)

Safety Data

• Hazardous Substances Data: 35717-21-6(Hazardous Substances Data)

Upstream product

• 96-43-5 2-thienyl chloride 
• 591-50-4 iodobenzene 
• 98-09-9 benzenesulfonyl chloride 
• 768-32-1 trimethylphenylsilane 
• 554-14-3 2-Methylthiophene 
• 98-80-6 phenylboronic acid 
• 2404-87-7 3-phenylthiophene 
• 3172-52-9 2,5-diclorothiophene 
• 71-43-2 benzene 

Downstream Products

• 3328-86-7 2,4-diphenylthiophene 
• 92-52-4 biphenyl 
• 143203-11-6 5-chloro-2-iodo-3-phenylthiophene 
• 134640-46-3 3,4'-diphenyl-2,2'-bithienyl 
• 158837-37-7 5',5''-dichloro-3'-phenyl-2,2':5,2''-terthiophene 
• 158837-36-6 5-chloro-3'-methyl-3-phenyl-2,2'-bithiophene 
• 158837-35-5 5-chloro-3-phenyl-2,2'-bithiophene 
• 134640-58-7 5-chloro-4,4'-diphenyl-2,2'-bithiophene 
• 108983-34-2 2-(p-methoxyphenyl)-4-phenylthiophene 
• 35717-22-7 2-chloro-3-phenylthiophene 
• 134640-41-8 5-chloro-3,4'-diphenyl-2,2'-bithienyl 
• 134640-51-0 4,4'-diphenyl-2,2'-bithiophene 
• 132981-59-0 2,5-dichloro-3-phenylthiophene 
• 2404-87-7 3-phenylthiophene 

Relevant articles and documents

Selective β-Arylation of Thiophenes with Aryl Iodides Catalyzed by Dinuclear Palladium Carboxylate Complexes

Novel dinuclear palladium complexes bearing acetoxy ligands were synthesized and characterized by X-ray crystal analysis. The complexes were utilized for the arylation of 2-ethylthiophene with iodobenzene to give ethylphenylthiophenes with high β selectiv

Benzenesulfonyl chlorides: New reagents for access to alternative regioisomers in palladium-catalysed direct arylations of thiophenes

The palladium-catalysed coupling of benzenesulfonyl chlorides with thiophene derivatives allows regioselective access to β-arylated thiophenes. The reaction proceeds with easily accessible catalyst, base and substrates, without oxidant or ligand and tolerates a variety of substituents on both the benzene and thiophene moieties.

Mechanistic studies on the Pd-catalyzed direct C-H arylation of 2-substituted thiophene derivatives with arylpalladium bipyridyl complexes

Direct C-H phenylation of 2-ethylthiophene and 2-chlorothiophene with PhPdI(bipy) complex to form either the corresponding 4-phenyl or 5-phenylthiophene derivative is studied under stoichiometric conditions using various Lewis acids as additives. It is sh