358741-44-3Relevant articles and documents
Study of the transient reactive Pd(IV) intermediate in the Pd(OAc) 2-catalyzed oxidative coupling reaction system by electrospray ionization tandem mass spectrometry
Zhu, Wei,Wang, Haoyang,Peng, Haihui,Liu, Guosheng,Guo, Yinlong
, p. 371 - 376 (2013)
Pd-catalyzed oxidative coupling reaction was of great importance in the aromatic C - H activation and the formation of new C - O and C - C bonds. Sanford has pioneered practical, directed C - H activation reactions employing Pd(OAc)2 as catalys
Chromium-Catalyzed Reductive Cleavage of Unactivated Aromatic and Benzylic C-O Bonds
Yuan, Shuqing,Ling, Liang,Tang, Jinghua,Luo, Meiming,Zeng, Xiaoming
supporting information, p. 3343 - 3350 (2021/07/02)
Reductive cleavage of aromatic and benzylic C-O bonds by chromium catalysis is reported. This deoxygenative reaction was promoted by low-cost CrCl 2precatalyst combined with poly(methyl hydrogen siloxane) as the mild reducing agent, providing a strategy in forming reduced motifs by cleavage of unactivated C-O bonds. A range of functional groups such as bromide, chloride, fluoride, hydroxyl, amino, and alkoxycarbonyl can be retained in the reduction.
Au(III)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis
Serra, Jordi,Parella, Teodor,Ribas, Xavi
, p. 946 - 952 (2017/02/10)
Au(iii)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C-O and C-N cross coupling catalysis. The crystal structures of cyclometalated neutral and cationic Au(iii) species are described and their key role in 2 ele
