36160-80-2Relevant articles and documents
Site-Specific Oxidation of (sp3)C-C(sp3)/H Bonds by NaNO2/HCl
Zhao, Jianyou,Shen, Tong,Sun, Zhihui,Wang, Nengyong,Yang, Le,Wu, Jintao,You, Huichao,Liu, Zhong-Quan
supporting information, p. 4057 - 4061 (2021/05/26)
A site-specific oxidation of (sp3)C-C(sp3) and (sp3)C-H bonds in aryl alkanes by the use of NaNO2/HCl was explored. The method is chemical-oxidant-free, transition-metal-free, uses water as the solvent, and proceeds under mild conditions, making it valuable and attractive to synthetic organic chemistry.
Conversion of tertiary amines to formamides in presence of dichlorocarbene and phenoxide ion
Yonovich, Minda,Sasson, Yoel
, p. 1875 - 1876 (2007/10/02)
Tertiary amines were found to be a convenient alkyl source for O-alkylation of substituted phenol, in presence of dichlorocarbene in a two-phase system.