5736-89-0

Basic information

• Product Name: 4'-BUTOXYACETOPHENONE
• Synonyms: 1-(4-butoxyphenyl)-ethanon;Acetophenone, 4'-butoxy-;Ethanone, 1-(4-butoxyphenyl)-;1-(4-butoxyphenyl)ethan-1-one;Bufexamac Imp. (EP);4-(N-BUTOXY)ACETOPHENONE;4'-N-BUTOXYACETOPHENONE;4'-BUTOXYACETOPHENONE
• CAS NO: 5736-89-0
• Molecular Formula: C₁₂H₁₆O₂
• Molecular Weight: 192.25
• EINECS: 227-248-4
• Product Categories: Aromatic Acetophenones & Derivatives (substituted);Adehydes, Acetals & Ketones;Anisoles, Alkyloxy Compounds & Phenylacetates;Acetophenones (Building Blocks for Liquid Crystals);Building Blocks for Liquid Crystals;Functional Materials;C11 to C12;Carbonyl Compounds;Ketones;Building Blocks;C11 to C12;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
• Mol File: 5736-89-0.mol
• Article Data: 33

Chemical Properties

• Melting Point: 25-27°C
• Boiling Point: 302-304 °C(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.017 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.000888mmHg at 25°C
• Refractive Index: n20/D 1.531(lit.)
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility: very faint turbidity in Methanol
• BRN: 637894
• CAS DataBase Reference: 4'-BUTOXYACETOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-BUTOXYACETOPHENONE(5736-89-0)
• EPA Substance Registry System: 4'-BUTOXYACETOPHENONE(5736-89-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/38
• Safety Statements: 26-36
• WGK Germany: 3
• TSCA: Yes
• HazardClass: IRRITANT
• Hazardous Substances Data: 5736-89-0(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 5736-89-0 differently. You can refer to the following data:
1. 1-(4-butoxyphenyl)ethanone is a useful research chemical.
2. 4′-Butoxyacetophenone (4-Butoxyacetophenone) may be used to synthesize:3,5-di-(4-butoxyphenyl)-1H-pyrazole(E)-1-(4-butoxyphenyl)-3-phenylprop-2-en-1-one5-aryl-6H-1,3,4-thiadiazine

Chemical Properties

Colorless liquid

General Description

4′-Butoxyacetophenone is a mildly electron-enriched phenylmethylketone.

InChI:InChI=1/C12H16O2/c1-3-4-9-14-12-7-5-11(6-8-12)10(2)13/h5-8H,3-4,9H2,1-2H3

Upstream product

• 1126-79-0 n-butyl phenyl ether 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 
• 109-65-9 1-bromo-butane 
• 99-93-4 4-Hydroxyacetophenone 
• 99-90-1 para-bromoacetophenone 
• 71-36-3 butan-1-ol 
• 542-69-8 1-iodo-butane 
• 100-67-4 potassium phenolate 
• 4766-57-8 tetra(n-butoxy)silane 
• 99-91-2 para-chloroacetophenone 
• 79887-15-3 1-butoxy-4-ethynylbenzene 
• 540-38-5 p-Iodophenol 
• 88075-18-7 4-(2-(trimethylsilyl)ethynyl)phenol 

Downstream Products

• 24239-62-1 1-(4-butoxy-phenyl)-3-dimethylamino-propan-1-one; hydrochloride 
• 74980-02-2 1-(4-butoxy-phenyl)-3-diethylamino-propan-1-one; hydrochloride 
• 536-43-6 dyclonine HCl 
• 53693-69-9 5,5'-bis-(4-butoxy-phenyl)-2,2'-p-phenylene-bis-oxazole 
• 78382-09-9 C₁₃H₂₀N₄OS 
• 92595-22-7 [1-(4-Butoxy-phenyl)-eth-(E)-ylidene]-phenyl-amine 
• 74196-67-1 (R)-2-[3-(4-Butoxy-phenyl)-3-oxo-propylamino]-propionic acid 
• 107265-32-7 1,3-Di-(p-n-butoxyphenyl)propane-1,3-dione 
• 93308-49-7 1-methyl-1-(4-butoxyphenyl)ethanol 
• 91563-69-8 1-(4-butoxy-phenyl)-ethanone oxime 
• 142074-33-7 3,4-di(p-butoxybenzoyl)furoxan 
• 53704-75-9 α-bromomethyl p(n-butyloxy)phenyl cetone 
• 91553-11-6 α-<4-Butyloxy-phenyl>-aethylamin 

Relevant articles and documents

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Defunctionalization of sp3 C–Heteroatom and sp3 C–C Bonds Enabled by Photoexcited Triplet Ketone Catalysts

A general strategy for enabling a light-induced defunctionalization of sp3 C–heteroatom and sp3 C–C bonds with triplet ketone catalysts and bipyridine additives is disclosed. This protocol is characterized by its broad scope without recourse to transition metal catalysts or stoichiometric exogeneous reductants, thus offering a complementary technique for activating σ sp3 C–C(heteroatom) bonds. Preliminary mechanistic studies suggest that the presence of 2,2′-bipyridines improves the lifetime of ketyl radical intermediates.

Site-Specific Oxidation of (sp3)C-C(sp3)/H Bonds by NaNO2/HCl

A site-specific oxidation of (sp3)C-C(sp3) and (sp3)C-H bonds in aryl alkanes by the use of NaNO2/HCl was explored. The method is chemical-oxidant-free, transition-metal-free, uses water as the solvent, and proceeds under mild conditions, making it valuable and attractive to synthetic organic chemistry.