36240-43-4

Basic information

• Product Name: diethyl 1-(trimethylsiloxy)-1-cyclohexylphosphonate
• Synonyms: diethyl 1-(trimethylsiloxy)-1-cyclohexylphosphonate
• CAS NO: 36240-43-4
• Molecular Weight: 308.43
• Mol File: 36240-43-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: diethyl 1-(trimethylsiloxy)-1-cyclohexylphosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 1-(trimethylsiloxy)-1-cyclohexylphosphonate(36240-43-4)
• EPA Substance Registry System: diethyl 1-(trimethylsiloxy)-1-cyclohexylphosphonate(36240-43-4)

Safety Data

• Hazardous Substances Data: 36240-43-4(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 286-20-4 cyclohexane-1,2-epoxide 
• 122-52-1 triethyl phosphite 
• 108-94-1 cyclohexanone 
• 13716-45-5 diethyl trimethylsilyl phosphite 

Downstream Products

• 85166-82-1 Methanesulfinic acid 1-(diethoxy-phosphoryl)-cyclohexyl ester 
• 51761-46-7 Methanesulfonic acid 1-(diethoxy-phosphoryl)-cyclohexyl ester 
• 42763-00-8 diethyl (1-hydroxycyclohexyl)phosphonate 

Relevant articles and documents

A novel procedure for conversion of epoxides to α -hydroxyphosphonates with a trialkylphosphite mediated by LiClO4

A new method has been developed for the direct conversion of epoxides to α-hydroxyphosphonates by the reaction of a trialkylphosphite with the epoxide in 5 M lithium perchlorate in diethyl ether (LPDE). The reaction is highly regioselective and efficient with excellent yields under mild and neutral conditions.