42763-00-8Relevant articles and documents
Synthesis, structure, and hydrophosphorylation of π-complexes of hexacarbonyltungsten(0) with cyclohexanone, cyclohexanethione, and N-cyclohexylideneaniline
Kuramshin,Pavlova,Cherkasov
, p. 1271 - 1279 (2005)
New carbonyl π-complexes of tungsten(0) with cyclohexanone, cyclohexanethione, and N-cyclohexylideneaniline were synthesized. Geometric and electronic parameters of the ligands, as well as energy parameters of the complex formation process, were determine
A simple heterogeneous catalyst for phosphite addition on carbonyl groups
Santacroce, Veronica,Paris, Emanuele,Cauzzi, Daniele,Maggi, Raimondo,Maestri, Giovanni
supporting information, p. 463 - 466 (2016/02/18)
A cheap and easily recoverable heterogeneous catalyst could efficiently trigger C-P bond formation by selective addition of phosphites to the carbonyl group of aldehydes and ketones. The reactions afford the desired products in good to excellent yields an
C-H hydroxylation of phosphonates with oxygen in [bmIm]OH to produce quaternary α-hydroxy phosphonates
Li, Xiangguang,Jin, Cheng,Gu, Lijun
, p. 2443 - 2447 (2015/05/04)
A highly efficient and mild [bmIm]OH-catalyzed α-hydroxylation of phosphonates using O2 as the oxygen source is described. The employment of ionic liquid under mild reaction conditions makes this transformation green and practical. Especially, this reaction provided a novel and convenient methodology for the construction of quaternary α-hydroxy phosphonates.
