7413-09-4Relevant articles and documents
Hydrophosphonylation of alkenes or nitriles by double radical transfer mediated by titanocene/propylene oxide
Midrier, Camille,Lantsoght, Mathias,Volle, Jean-No?l,Pirat, Jean-Luc,Virieux, David,Stevens, Christian V.
scheme or table, p. 6693 - 6696 (2012/01/04)
Hydrophosphonylation reactions have emerged as efficient processes for the functionalization of alkenes or alkynes. Synthesis of alkylphosphonates was achieved by an original double radical transfer mediated by titanocene and propylene oxide. By the same way, nitriles which are considered as inert functions in radical process lead to aminobisphosphonates.
Reactions of dialkyl phosphonates with hexacarbonylmolybdenum(0) and hexacarbonyltungsten(0). Structure of intermediates in the catalytic phosphorylation of alkenes
Kuramshin,Nikolaev,Cherkasov
, p. 1744 - 1749 (2007/10/03)
Reactions of dialkyl phosphonates with catalytic precursors in the phosphorylation of alkenes and aryl halides, homoligand molybdenum(0) and tungsten(0) carbonyl complexes, were studied by quantum-chemical and spectroscopic (IR and NMR) methods. Schemes w
Addition of dialkyl hydrogen phosphites to alkenes in the presence of carbonyl complexes of chromium subgroup metals and iron
Kuramshin,Kuramshina,Cherkasov
, p. 354 - 358 (2007/10/03)
Depending on the reactant ratio and order of their mixing, reactions of dialkyl hydrogen phosphite with alkenes in the presence of catalytic amounts of homoligand carbonyl complexes of iron or chromium subgroup metals yield phosphonates by two pathways: r
