362624-03-1

Basic information

• Product Name: (E)-4-[2-(2-Benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-but-2-en-1-ol
• Synonyms: (E)-4-[2-(2-Benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-but-2-en-1-ol
• CAS NO: 362624-03-1
• Molecular Weight: 278.348
• Mol File: 362624-03-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-4-[2-(2-Benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-but-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-[2-(2-Benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-but-2-en-1-ol(362624-03-1)
• EPA Substance Registry System: (E)-4-[2-(2-Benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-but-2-en-1-ol(362624-03-1)

Safety Data

• Hazardous Substances Data: 362624-03-1(Hazardous Substances Data)

Upstream product

• 362624-02-0 (E)-4-[2-(2-Benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-but-2-enoic acid ethyl ester 
• 5694-95-1 2-(2-(2-hydroxyethyl)-1,3-dioxolan-2-yl)ethanol 
• 312326-47-9 2-[2-[2-(benzyloxy)ethyl]-1,3-dioxolan-2-yl]ethanol 
• 312326-48-0 [2-(2-benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-acetaldehyde 
• 1830-54-2 3-oxopentanedioic acid dimethyl ester 
• 6506-31-6 dimethyl acetonedicarboxylate ethylene ketal 

Downstream Products

• 362624-14-4 (E)-2-[(4S,6R)-6-((S)-2,4-Bis-benzyloxy-butyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-6-{2-[(R)-2-(tert-butyl-dimethyl-silanyloxy)-3-methoxymethoxy-propyl]-[1,3]dioxolan-2-yl}-2-methyl-hex-4-en-3-one 
• 362624-15-5 3-[(4S,6R)-6-((S)-2,4-Bis-benzyloxy-butyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-1-((7R,9R)-9-methoxymethoxymethyl-1,4,8-trioxa-spiro[4.5]dec-7-yl)-3-methyl-butan-2-one 
• 362624-08-6 4-[2-(2-benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-3-(tert-butyl-dimethyl-silanyloxy)-butane-1,2-diol 
• 362624-11-1 {2-[2-(2-benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-1-methoxymethoxymethyl-ethoxy}-tert-butyl-dimethyl-silane 
• 362624-10-0 3-[2-(2-benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-2-(tert-butyl-dimethyl-silanyloxy)-propan-1-ol 
• 362624-07-5 {1-[2-(2-benzyloxy-ethyl)-[1,3]dioxolan-2-ylmethyl]-allyloxy}-tert-butyl-dimethyl-silane 
• 362624-09-7 3-[2-(2-benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-2-(tert-butyl-dimethyl-silanyloxy)-propionaldehyde 
• 362624-05-3 2-(2-Benzyloxy-ethyl)-2-((2R,3S)-3-iodomethyl-oxiranylmethyl)-[1,3]dioxolane 
• 362624-06-4 (R)-1-[2-(2-Benzyloxy-ethyl)-[1,3]dioxolan-2-yl]-but-3-en-2-ol 
• 362624-04-2 {(2R,3R)-3-[2-(2-Benzyloxy-ethyl)-[1,3]dioxolan-2-ylmethyl]-oxiranyl}-methanol 

Relevant articles and documents

An approach towards the C1-C16 fragment of antineoplastic macrolide bryostatins by kinetic resolution of a racemic terminal epoxide using Jacobsen's catalyst

A stereo- and enantioselective approach towards the C1-C16 fragment of bryostatins is reported using Jacobsen's catalyst for kinetic resolution of a terminal epoxide, a Horner-Wadsworth-Emmons coupling reaction and a 1,4-Michael type cyclization as key steps.