36804-12-3

Basic information

• Product Name: 2-Propen-1-one, 3-[3,4-bis(methoxymethoxy)phenyl]-1-[2,4,6-tris(methoxymethoxy)phenyl ]-, (2E)-
• CAS NO: 36804-12-3
• Molecular Formula: C25H32O11
• Molecular Weight: 508.522
• Mol File: 36804-12-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-one, 3-[3,4-bis(methoxymethoxy)phenyl]-1-[2,4,6-tris(methoxymethoxy)phenyl ]-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-one, 3-[3,4-bis(methoxymethoxy)phenyl]-1-[2,4,6-tris(methoxymethoxy)phenyl ]-, (2E)-(36804-12-3)
• EPA Substance Registry System: 2-Propen-1-one, 3-[3,4-bis(methoxymethoxy)phenyl]-1-[2,4,6-tris(methoxymethoxy)phenyl ]-, (2E)-(36804-12-3)

Safety Data

• Hazardous Substances Data: 36804-12-3(Hazardous Substances Data)

Upstream product

• 850177-05-8 (E)-3-[3,4-bis(methoxymethoxy)phenyl]acrylic acid 
• 120677-47-6 1,3,5-tris(methoxymethoxy)benzene 
• 331-39-5 caffeic acid 
• 108-73-6 3,5-dihydroxyphenol 
• 65490-09-7 2'-hydroxy-4',6'-bis(methoxymethoxy)acetophenone 
• 36804-11-2 2,4,6-tri-MOM phloracetophenone 
• 6515-06-6 3,4-bis-methoxymethoxy-benzaldehyde 

Downstream Products

• 215257-15-1 3,3',4',5,7-pentahydroxy flavanone 
• 1186493-51-5 (2S,3S)-3',4',5,7-tetrahydroxy-2,3-dihydroflavonol-6-C-β,D-glucopyranoside 
• 112494-39-0 (2R,3R)-(+)-3',4',5,7-tetrahydroxydihydroflavonol-6-C-β-D-glucopyranoside 
• 480-18-2 (2S,3S)-taxifolin 3-O-β-D-glucoside 
• 480-18-2 taxifolin 
• 480-18-2 (+/-)-taxifolin 

Relevant articles and documents

Total Synthesis of the Natural Products Ulmoside A and (2 R,3 R)-Taxifolin-6- C -β- d -glucopyranoside

An efficient first total synthesis of highly polar ulmoside A and (2 R,3 R)-taxifolin-6- C -β- d -glucopyranoside, useful for the prevention of metabolic disorders, has been described. Key elements of the synthesis include a Sc(OTf) 3-catalyzed regio- and stereoselective C -glycosidation on taxifolin in 35percent yield with d -glucose and chiral semipreparative reverse-phase high-performance liquid chromatography (HPLC) for the separation of both taxifolins and the diastereomeric mixture of taxifolin-6- C -β- d -glucopyranosides. Correlation of the analytical data of synthetic ulmoside A and its diastereomer with a natural ulmoside A sample confirmed the assigned absolute stereochemistry of the natural products.