371-35-7

Basic information

• Product Name: Phenol, 4-fluoro-, sodium salt
• CAS NO: 371-35-7
• Molecular Formula: C6H5FO.Na
• Molecular Weight: 134.085
• Mol File: 371-35-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Phenol, 4-fluoro-, sodium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 4-fluoro-, sodium salt(371-35-7)
• EPA Substance Registry System: Phenol, 4-fluoro-, sodium salt(371-35-7)

Safety Data

• Hazardous Substances Data: 371-35-7(Hazardous Substances Data)

Upstream product

• 371-41-5 4-Fluorophenol 
• 7646-69-7 sodium hydride 
• 2714-93-4 4-fluorophenyl benzoate 

Downstream Products

• 61372-59-6 1-Fluoro-4-(4-methoxy-butoxy)-benzene 
• 14467-22-2 4-(4-Fluor-phenoxyacetoxy-methyl)-1-phospha-2,6,7-trioxa-bicyclo<2.2.2>octan-1-sulfid 
• 13990-72-2 1-allyloxy-4-fluorobenzene 
• 367-32-8 4-fluoropyrocatechol 
• 147300-09-2 3,5-difluorobenzene-1,2-diol 
• 1428096-23-4 [(κ³-P,N,P-(4-Me-2-(ⁱPr₂P)-C₆H₃)₂N)Rh(OC₆H₄F-p)] 
• 1329709-99-0 C₂₁H₂₈FN₃O 
• 1190714-67-0 [PPN][(NO)2Fe(OC₆H₄-p-F)2] 
• 38117-54-3 cyclopentadienyl iron(II) dicarbonyl dimer 
• 177712-38-8 [(η5-C5H5)Fe(CO)2(trans-PhCC(OC6H4-F-p)Ph)] 

Relevant articles and documents

Selective ortho-hydroxylation-defluorination of 2-fluorophenolates with a Bis(μ-oxo)dicopper(III) species

The bis(μ-oxo)dicopper(III) species [CuIII 2(μ-O)2(m-XYLMeAN)]2+ (1) promotes the electrophilic ortho-hydroxylation-defluorination of 2-fluorophenolates to give the corresponding catechols, a reaction that is not accomplishable with a (η2:η2-O2) dicopper(II) complex. Isotopic labeling studies show that the incoming oxygen atom originates from the bis(μ-oxo) unit. Ortho-hydroxylation-defluorination occurs selectively in intramolecular competition with other ortho-substituents such as chlorine or bromine. O in, F out: [CuIII2(μ-O) 2(m-XYLMeAN)]2+ is a bis(μ-oxo)dicopper(III) species and promotes the electrophilic ortho-hydroxylation-defluorination of 2-fluorophenolates to give the corresponding catechols. Isotopic labeling shows that the incoming oxygen atom originates from the bis(μ-oxo) unit. Ortho-hydroxylation-defluorination occurs selectively in intramolecular competition with other ortho-substituents such as chlorine or bromine.

PHOSPHAZENE COMPOUND, LUBRICANT AND MAGNETIC RECORDING MEDIUM HAVING SUCH COMPOUND, METHOD OF PREPARATION, AND METHOD OF LUBRICATION

A compound of the formula: (I) is provided, where R is selected from CF3, F, and H, and m is an integer from 1 to 22. The compound may be prepared by reacting a first reactant with a second reactant in a solution, where the first reactant is a 2,4-dichloro-2,4,6,6- tetra(aryloxy)-1,3,5-triaza-2,4,6-triphosphorine, and the second reactant is a perfluoropolyether of the formula CF3CF2CF2O(CF2CF2CF2O)mCF2CF2CH2OH. The aryloxy is selected from 4-(trifluoromethyl)phenoxy (p -CF3-C6H4O), 4-fluorophenoxy (p-F-C6H4O), and phenoxy (C6H5O). The first reactant may be prepared by reacting 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine with a phenoxide. The compound may be used in a lubricant for lubricating a surface. The lubricant may be applied to a recording surface in a magnetic recording device including a recording medium.

EFFECT OF THE STRUCTURE OF THE LEAVING GROUP, MEDIUM, AND TEMPERATURE ON THE ALKALINE HYDROLYSIS OF PHENYL BENZOATES IN WATER-DIOXANE MIXTURES

A spectrophotometric study was carried out on the kinetics of the alkaline hydrolysis of a series of para-substituted phenyl benzoates PhCO2C6H4X-p in water, 30 and 70 vol. percent aqueous dioxane at 15 deg, 25 deg, and 55 deg C.The bimolecular rate constants depend on the medium composition, temperature, and structure of the leaving group.It is of value to apply linear free energy (LFE) principles in studying these factors, which permits description of the entire set of experimental data by a single multidimensional regression equation.The Arrhenius equation parameters were calculated and this reaction series was shown to be compensated, in contrast to the alkaline hydrolysis of phenyl acetates.The dependence of the ρ constants in the Hammett-Taft equation on the medium composition and temperature indicate that this value is not a linear function of the extent of formation and breakage of bonds in the transition state.