37630-43-6

Basic information

• Product Name: [(Z)-2-methylsulfonylethenyl]benzene
• Synonyms: [(Z)-2-methylsulfonylethenyl]benzene
• CAS NO: 37630-43-6
• Molecular Formula: C₉H₁₀O₂S
• Molecular Weight: 0
• Mol File: 37630-43-6.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 368.4°Cat760mmHg
• Flash Point: 227.7°C
• Appearance: /
• Density: 1.203g/cm³
• Vapor Pressure: 2.71E-05mmHg at 25°C
• Refractive Index: 1.565
• CAS DataBase Reference: [(Z)-2-methylsulfonylethenyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(Z)-2-methylsulfonylethenyl]benzene(37630-43-6)
• EPA Substance Registry System: [(Z)-2-methylsulfonylethenyl]benzene(37630-43-6)

Safety Data

• Hazardous Substances Data: 37630-43-6(Hazardous Substances Data)

Usage

Description

[(Z)-2-methylsulfonylethenyl]benzene, also known as benzyl methyl sulfoxide, is a chemical compound characterized by its molecular formula C9H10OS. It is a colorless liquid with a strong odor and is recognized for its versatile applications across various industries.

Uses

Used in Pharmaceutical Industry:
[(Z)-2-methylsulfonylethenyl]benzene is used as an intermediate for the production of pharmaceuticals and other organic compounds. Its unique chemical properties make it a valuable component in the synthesis of various medicinal agents.
Used in Solvent Applications:
This chemical compound serves as a solvent in numerous chemical processes, facilitating reactions and improving the efficiency of production.
Used in Perfumery and Aromatics Industry:
[(Z)-2-methylsulfonylethenyl]benzene is utilized in the manufacturing process of perfumes, dyes, and other aromatic products, capitalizing on its strong odor to enhance the fragrance and appeal of these products.
Used in Agriculture:
Although its use is still under investigation, [(Z)-2-methylsulfonylethenyl]benzene has shown potential as a herbicide and fungicide. It is believed to inhibit the growth of certain plant pathogens, making it a possible candidate for agricultural applications.
However, it is crucial to handle [(Z)-2-methylsulfonylethenyl]benzene with caution due to its potential irritant properties and the risks associated with ingestion or inhalation in large quantities.

InChI:InChI=1/C9H10O2S/c1-12(10,11)8-7-9-5-3-2-4-6-9/h2-8H,1H3/b8-7-

Upstream product

• 35822-50-5 (Z)-methyl(styryl)sulfane 
• 15436-11-0 (E)-methyl styryl sulfone 
• 185844-50-2 ((Z)-1-Methanesulfonyl-2-phenyl-vinyl)-trimethyl-silane 
• 56583-94-9 (phenylacetyl)trimethylsilane 
• 185844-35-3 (Z)-2-phenyl-1-trimethylsilylethenenethiol 
• 185844-37-5 Trimethyl-((Z)-1-methylsulfanyl-2-phenyl-vinyl)-silane 
• 536-74-3 phenylacetylene 
• 7714-33-2 methyl phenylethynyl sulfide 
• 124-63-0 methanesulfonyl chloride 
• 2170-06-1 1-Phenyl-2-(trimethylsilyl)acetylene 

Downstream Products

• 6079-56-7 (2-(methylsulfonyl)ethyl)benzene 
• 85978-10-5 (4R,5R)-5-Methanesulfonyl-3,4-diphenyl-4,5-dihydro-isoxazole 
• 85978-14-9 (4R,5R)-4-Methanesulfonyl-3,5-diphenyl-4,5-dihydro-isoxazole 
• 69263-05-4 2-(1-Methylsulfonyl-2-phenylaethyl)cyclohexanon 
• 69263-11-2 2-(2-Methylsulfonyl-1-phenylaethyl)cyclohexanon 
• 74994-71-1 (2R*,αR*)-trans-pyrrolidin-1-yl-2-<α-(methylsulphonyl)-β-phenylethyl>-4-t-butylcyclohex-6-ene 
• 15436-11-0 (E)-methyl styryl sulfone 
• 77204-66-1 methyl (α-ethoxy-β-phenylethyl)sulphone 
• 69263-12-3 4-phenyl-Δ^4a(8a)-2-thiaoctalin 2,2 dioxide 
• 69263-13-4 8a-α-hydroxy-4-β-phenyl-trans-2-thiadecalin 2,2 dioxide 
• 69263-13-4 8a-β-hydroxy-4-β-phenyl-cis-2-thiadecalin 2,2 dioxide 
• 74994-73-3 (2R^*,αR^*)-cis-4-t-butyl-2-(α-phenyl-β-methylsulphonylethyl)cyclohexanone 
• 74994-73-3 (2S^*,αR^*)-trans 4-t-butyl-2-(α-phenyl-β-methylsulphonylethyl)cyclohexanone 
• 75011-17-5 6α-t-butyl-8aα-hydroxy-4β-phenyl-trans-perhydro-2-benzothiin 

Relevant articles and documents

Silver(I)-mediated reaction of trimethylsilylated arylacetylenes with sulfonyl chlorides: Unexpected formation of vinyl sulfones

A novel reaction of trimethylsilylated arylacetylenes with sulfonyl chlorides was performed in the presence of silver nitrate or triflate. Conjugated vinyl sulfones as dramatic products were obtained in moderate yields and with Z-selectivity. A free radical mechanism has been proposed to account for the formation of the products.

Chemistry of silyl thioketones. Part 10. Synthesis and reactivity of α-silyl vinyl sulfldes

Aliphatic silyl thioketones containing an α-hydrogen atom undergo enethiolization to Z-α-silyl enethiols 2. Compounds 2 react with a variety of halides R3X to give open-chain α-silyl vinyl sulfides 3. Protiodesilylation of 3 was achieved upon treatment with fluoride ion to give vinyl sulfides 4. Reaction of 3 with Grignard reagents, in the presence of an appropriate nickel catalyst, results in a series of vinylsilanes 5 with a specific geometry.

Zur Darstellung substituierter cis-β-Styryl-methyl-sulfone

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