382136-74-5

Basic information

• Product Name: (Z)-1-benzyl-hexadecan-5-ene
• Synonyms: (Z)-1-benzyl-hexadecan-5-ene
• CAS NO: 382136-74-5
• Molecular Weight: 330.554
• Mol File: 382136-74-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-1-benzyl-hexadecan-5-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-benzyl-hexadecan-5-ene(382136-74-5)
• EPA Substance Registry System: (Z)-1-benzyl-hexadecan-5-ene(382136-74-5)

Safety Data

• Hazardous Substances Data: 382136-74-5(Hazardous Substances Data)

Upstream product

• 693-67-4 bromoundecane 
• 78999-24-3 5-benzyloxy-1-pentanal 
• 60669-22-9 n-undecyltriphenylphosphonium bromide 

Downstream Products

• 89102-35-2 (5R*,6S*)-6-hydroxyhexadecan-5-olide 
• 81792-36-1 racemic erythro 6-acetoxy-5-hexadecanolide 

Relevant articles and documents

Syntheses of 5-hexadecanolide, 6-acetoxy-5-hexadecanolide and tanikolide

Total syntheses of 5-hexadecanolide (1), 6-acetoxy-5-hexadecanolide (2) and tanikolide (3) are described. 1-Bromoundecane (4) and 5-benzyl-1-pentanal (5) were chosen as starting materials. Wittig olefination and Grignard addition 4 and 5 afforded the 16-carbon skeleton, which underwent a series of functional group transformations to give δ-lactone derivatives 1, 2 and 3.