38383-51-6

Basic information

• Product Name: 3-vinylbiphenyl
• Synonyms: 3-vinylbiphenyl;1,1'-Biphenyl, 3-ethenyl-;1-Ethenyl-3-phenylbenzene
• CAS NO: 38383-51-6
• Molecular Formula: C₁₄H₁₂
• Molecular Weight: 180.24508
• EINECS: -0
• Mol File: 38383-51-6.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 3-vinylbiphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 3-vinylbiphenyl(38383-51-6)
• EPA Substance Registry System: 3-vinylbiphenyl(38383-51-6)

Safety Data

• Hazardous Substances Data: 38383-51-6(Hazardous Substances Data)

Upstream product

• 58114-12-8 (RS)-1-([1,1'-biphenyl]-3-yl)ethanol 
• 111-34-2 -butyl vinyl ether 
• 55365-18-9 biphenyl-2-yl-lithium 
• 103068-18-4 [(1,1'-biphenyl)-3-yl]magnesium bromide 
• 108-05-4 vinyl acetate 
• 5122-95-2 3-Biphenylboronic acid 
• 1204-60-0 biphenyl-3-carbaldehyde 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 58650-11-6 3-Biphenylylacetylene 
• 108-86-1 bromobenzene 
• 15016-43-0 3-vinylphenylboronic acid 
• 98-80-6 phenylboronic acid 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 3132-99-8 m-bromobenzoic aldehyde 

Downstream Products

• 1582789-82-9 (E)-2-(2-([1,1'-biphenyl]-3-yl)vinyl)benzo[d]oxazole 

Relevant articles and documents

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent

A nickel-catalyzed reductive cross-coupling has been achieved using (hetero)aryl bromides and vinyl acetate as the coupling partners. This mild, applicable method provides a reliable access to a variety of vinyl arenes, heteroarenes, and benzoheterocycles, which should expand the chemical space of precursors to fine chemicals and polymers. Importantly, a sustainable solvent, dimethyl isosorbide, is used, making this protocol more attractive from the point of view of green chemistry.

Ni: Vs. Pd in Suzuki-Miyaura sp2-sp2 cross-coupling: A head-to-head study in a comparable precatalyst/ligand system

The Suzuki-Miyaura reaction is a cornerstone method for sp2-sp2 cross-coupling in industry. There has been a concerted effort to enable the use of Ni catalysis as an alternative to Pd in order to mitigate cost and improve sustainability. Despite significant advances, ligand development for Ni-catalyzed Suzuki-Miyaura cross-coupling remains underdeveloped when compared to Pd and, as a consequence, ligands for Ni-catalyzed processes are typically taken from the Pd arena. In this study we evaluate the effect of using a similar Ni and Pd precatalyst based on a common bidentate ligand (dppf) in a head-to-head format for the most common type of biaryl couplings, establishing the practical implications of direct replacement of Pd with Ni, and identifying the potential origins of these observations in a mechanistic context.

Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes

The CF3 radical was generated from the reaction of S-(trifluoromethyl)diphenylsulfonium triflate with Na2S 2O4 or HOCH2SO2Na under suitable conditions without further reduction. Based on this, a method for the synthesis of α-trifluoromethylated ketones has been successfully developed.