38503-22-9

Basic information

• Product Name: trans-2-(m-chlorophenyl)-3-phenyloxirane
• CAS NO: 38503-22-9
• Molecular Weight: 230.694
• Mol File: 38503-22-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-2-(m-chlorophenyl)-3-phenyloxirane(CAS DataBase Reference)
• NIST Chemistry Reference: trans-2-(m-chlorophenyl)-3-phenyloxirane(38503-22-9)
• EPA Substance Registry System: trans-2-(m-chlorophenyl)-3-phenyloxirane(38503-22-9)

Safety Data

• Hazardous Substances Data: 38503-22-9(Hazardous Substances Data)

Upstream product

• 1334478-48-6 1-benzyl-3-methylbenzotriazolium iodide 
• 587-04-2 m-Chlorobenzaldehyde 
• 38503-22-9 trans-2-(m-chlorophenyl)-3-phenyloxirane 
• 124-38-9 carbon dioxide 
• 100-39-0 benzyl bromide 
• 14064-43-8 (E)-3-chlorostilbene 

Downstream Products

• 38503-22-9 trans-2-(m-chlorophenyl)-3-phenyloxirane 

Relevant articles and documents

Chiral Macrocyclic Organocatalysts for Kinetic Resolution of Disubstituted Epoxides with Carbon Dioxide

Among chiral macrocycles 1 synthesized, 1m with the 3,5-bis(trifluoromethyl)phenylethynyl group was the best organocatalyst for the enantioselective synthesis of cyclic carbonates from disubstituted or monosubstituted epoxides and CO2. The X-ray crystal structure of 1m revealed a well-defined chiral cavity with multiple hydrogen-bonding sites that is suitable for the enantioselective activation of epoxides. A catalytic cycle proposed was supported by DFT calculations.