3993-32-6Relevant articles and documents
Encapsulated molecular catalysts in polysiloxane gels: Ruthenium cluster-catalyzed isomerization of alkenes
Motoyama, Yukihiro,Abe, Motonori,Kamo, Kazuyuki,Kosako, Yusuke,Nagashima, Hideo
supporting information; experimental part, p. 5321 - 5323 (2009/03/11)
Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (μ3, η2,η3,η5-acenaphthylene)Ru 3(CO)7, and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species. The Royal Society of Chemistry.
Regioselectivity in aromatic Claisen rearrangements
Gozzo, Fabio Cesar,Fernandes, Sergio Antonio,Rodrigues, Denise Cristina,Eberlin, Marcos Nogueira,Marsaioli, Anita Jocelyne
, p. 5493 - 5499 (2007/10/03)
Theoretical calculations and the isomeric product composition for a series of eight meta-substituted allyl aryl ethers confirm the reliability of a new 1H NMR methodology used to predict aromatic Claisen regioselectivity from ground-state confo