409360-03-8

Basic information

• Product Name: 2-bromo-3,5-dimethoxy-1-triisopropylsiloxymethylbenzene
• Synonyms: 2-bromo-3,5-dimethoxy-1-triisopropylsiloxymethylbenzene
• CAS NO: 409360-03-8
• Molecular Weight: 403.432
• Mol File: 409360-03-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-bromo-3,5-dimethoxy-1-triisopropylsiloxymethylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-3,5-dimethoxy-1-triisopropylsiloxymethylbenzene(409360-03-8)
• EPA Substance Registry System: 2-bromo-3,5-dimethoxy-1-triisopropylsiloxymethylbenzene(409360-03-8)

Safety Data

• Hazardous Substances Data: 409360-03-8(Hazardous Substances Data)

Upstream product

• 705-76-0 3,5-dimethoxybenzyl alcohol 
• 13154-24-0 triisopropylsilyl chloride 
• 74726-76-4 2-bromo-3,5-dimethoxybenzyl alcohol 

Relevant articles and documents

Syntheses of cyclotriveratrylene analogues and their long elusive triketone congeners

Although interest in cyclotriveratrylene and its analogues has been significant, limitations in the ability to adjust its structure fully have hampered studies into their complete range of properties. A unique strategy to synthesize a previously unobtainable cyclotriveratrylene analogue and a procedure which adjusts the inner methylene bridges of that material to a triketone is reported. A second triketone synthesis and computational studies indicate the parameters needed for success.

Dilithiation of arenetricarbonylchromium(0) complexes with enantioselective quench: Application to chiral biaryl synthesis

Dilithiation of methoxymethoxyarenetricarbonylchromium complexes with 2.5 equiv. of butyllithium and 6 equiv. of (-)-sparteine followed by enantioselective electrophilic quench gave the planar chiral (R)-complexes in up to 95% ee. This technique was applied to the synthesis of the chromium complexes of biaryl analogues 7 of actinoidinic acid.