4098-70-8

Basic information

• Product Name: cis-ethyl N-2-chlorocyclohexylcarbamate
• CAS NO: 4098-70-8
• Molecular Weight: 205.685
• Mol File: 4098-70-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: cis-ethyl N-2-chlorocyclohexylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: cis-ethyl N-2-chlorocyclohexylcarbamate(4098-70-8)
• EPA Substance Registry System: cis-ethyl N-2-chlorocyclohexylcarbamate(4098-70-8)

Safety Data

• Hazardous Substances Data: 4098-70-8(Hazardous Substances Data)

Upstream product

• 931-12-4 trans-2-chloro-cyclohexylamine 
• 541-41-3 chloroformic acid ethyl ester 
• 16844-21-6 N-Chlorourethan 
• 110-83-8 cyclohexene 
• 13698-16-3 ethyl N,N-dichlorocarbamate 
• 931-12-4 (+/-)-cis-2-chlorocyclohexan-1-amine 

Relevant articles and documents

CHROMIUM(II) PROMOTED ADDITION OF N-CHLOROCARBAMATES TO ALKENES

Ethyl N-chloro-N-methylcarbamate has been shown to produce adducts with some alkenes.The role of the chromium(II) species in the reaction is discussed.

THE ELECTROCHEMICAL REDUCTION OF N-FLUOROETHANS IN ACETONITRILE. THE GENERATION OF CARBETHOXYNITRENE

The electrochemical reduction of N-fluoro-N-methylurethan (1a) and N-fluorourethan (2a) in acetonitrile generates the amide anion and fluoride ion.Both the fluoride and the amide react with the starting N-fluoroamide either as bases or as nucleophiles.Many products are formed and the coulometric results are low (0.5 to 0.7 F/mol).In the case of NFU (2a), abstraction of the proton on nitrogen both by the urethan anion and the fluoride anion generates the conjugate base EtOCOF (7) which immediately undergoes α-elimination of the fluoride ion to give carbethoxynitrene (11).This nitrene was generated also by treating NFU (2a) with a base such as triethylamine of lithium hydride.The α-elimination of F1- from EtOCOF is much easier than α-elimination of Cl1- from EtOCOCl.