931-12-4Relevant articles and documents
Strong hyperconjugative interactions limit solvent and substituent influence on conformational equilibrium: The case of cis-2-halocyclohexylamines
Francisco, Camila B.,Fernandes, Cleverton S.,de Melo, Ulisses Z.,Rittner, Roberto,Gauze, Gisele F.,Basso, Ernani A.
, p. 818 - 829 (2019)
The presence of strong stereoelectronic interactions involving the substituents in cis-2-substituted cyclohexanes may lead to results different from those expected. In this work, we studied the conformational behavior of cis-2-fluoro- (F), cis-2-chloro- (
Catalytic asymmetric ring openings of Meso and terminal aziridines with halides mediated by chiral 1,2,3-triazolium silicates
Ohmatsu, Kohsuke,Hamajima, Yuta,Ooi, Takashi
supporting information; experimental part, p. 8794 - 8797 (2012/07/02)
Catalytic asymmetric chloride and bromide ring openings of meso aziridines with trimethylsilyl halides have been developed using modular chiral 1,2,3-triazolium chlorides as catalysts. Control experiments suggest the reaction pathway involving hypervalent