41029-45-2

Basic information

• Product Name: Allyl triflate
• Synonyms: Allyl triflate;Allyl Trifluoromethanesulfonate
• CAS NO: 41029-45-2
• Molecular Formula: C₄H₅F₃O₃S
• Molecular Weight: 190.1409096
• Mol File: 41029-45-2.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 16.6°C
• Appearance: /
• Density: 1.456 (estimate)
• CAS DataBase Reference: Allyl triflate(CAS DataBase Reference)
• NIST Chemistry Reference: Allyl triflate(41029-45-2)
• EPA Substance Registry System: Allyl triflate(41029-45-2)

Safety Data

• Hazardous Substances Data: 41029-45-2(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 42, p. 3109, 1977 DOI: 10.1021/jo00439a001

Upstream product

• 556-56-9 allyl iodid 
• 2923-28-6 silver trifluoromethanesulfonate 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 107-18-6 allyl alcohol 

Downstream Products

• 50998-72-6 C₁₀H₁₁NO 
• 198546-63-3 (4-Methoxy-phenyl)-((R)-1-methyl-1-phenyl-but-3-enyl)-carbamic acid tert-butyl ester 
• 198546-61-1 (4-Methoxy-phenyl)-((S)-1-methyl-1-phenyl-but-3-enyl)-carbamic acid tert-butyl ester 
• 267408-63-9 N-(2'-Bromophenyl)-N-prop-2-enylpropynamide 
• 328059-76-3 C₅₄H₈₃NO₁₃ 
• 1030313-85-9 methyl 3-[allyl(benzyl)amino]-2,3-dideoxy-2-methylene-4,5-O-(1-methylethylidene)-D-threo-pentanoate 
• 190450-07-8 (CO)5Cr(C(CCC₆H₅)OCH₂CHCH₂) 
• 190450-06-7 (CO)5W(C(CCC₆H₅)OCH₂CHCH₂) 
• 1158445-86-3 CF₃O₃S^(1-)*C₁₇H₂₄NO₂⁽¹⁺⁾ 

Relevant articles and documents

A unified approach to quinolizinium cations and related systems by ring-closing metathesis

(Chemical Equation Presented) The first example of an olefin ring-closing metathesis reaction on cationic heteroaromatic systems is described. Dihydroquinolizinium cations and a variety of related cationic systems are synthesized in an efficient approach from N-alkenyl α-vinyl azinium salts using Grubbs' catalysts.

Synthesis of tertiary alkyl fluorides and chlorides by site-selective nucleophilic ring-opening reaction of α-aryl azetidinium salts

Site-selective nucleophilic ring-opening reactions of 2-arylazetidine-2-carboxylic acid ester-derived tetraalkyl ammonium salts2with tetrabutylammonium halides (Bu4NX) to give tertiary alkyl halides are successfully demonstrated. For example, a nucleophilic ring-opening reaction of 2-(o-tolyl) derivative2awith 1.2 equivalents of tetrabutylammonium fluoride (Bu4NF) in THF at 60 °C preferentially proceeded at a more substituted carbon atom (2-position) compared to a less-substituted carbon atom (4-position) and affordedtert-butyl 4-(dimethylamino)-2-fluoro-2-(o-tolyl)butanoate3aain 71% yield as the corresponding tertiary alkyl fluoride. This result was applied to synthesize optically active organofluorine compounds starting from commercially available (R)-1-phenylethylamine.

Conformationally restricted pyrrolidines by intramolecular [2+2] photocycloaddition reactions

Intramolecular [2+2] photocycloaddition reactions of diversely substituted N-Boc protected 4-(allylaminomethyl)-2(5H)-furanones resulted in rigid products (53-75%) with three spatially defined positions for further functionalisation. The Royal Society of Chemistry.