41043-88-3

Basic information

• Product Name: ACETIC ACID 4-OXO-CYCLOHEXYL ESTER
• Synonyms: ACETIC ACID 4-OXO-CYCLOHEXYL ESTER;Cyclohexanone,4-(acetyloxy)-;4-Oxocyclohexyl acetate;4-(acetyloxy)cyclohexanone
• CAS NO: 41043-88-3
• Molecular Formula: C₈H₁₂O₃
• Molecular Weight: 156.18
• Product Categories: Miscellaneous
• Mol File: 41043-88-3.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 230.8 °C at 760 mmHg
• Flash Point: 94.9 °C
• Appearance: /
• Density: 1.08 g/cm³
• Vapor Pressure: 0.0646mmHg at 25°C
• Refractive Index: 1.455
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: ACETIC ACID 4-OXO-CYCLOHEXYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETIC ACID 4-OXO-CYCLOHEXYL ESTER(41043-88-3)
• EPA Substance Registry System: ACETIC ACID 4-OXO-CYCLOHEXYL ESTER(41043-88-3)

Safety Data

• Hazardous Substances Data: 41043-88-3(Hazardous Substances Data)

Usage

General Description

ACETIC ACID 4-OXO-CYCLOHEXYL ESTER is an organic compound that is commonly used as a flavoring agent in the food industry. It is also used in the production of perfumes and other fragrance products. This chemical is known for its fruity and sweet odor, making it a popular choice for enhancing the scent of various consumer products. ACETIC ACID 4-OXO-CYCLOHEXYL ESTER is considered safe for use in food and fragrance applications when used in accordance with regulations and guidelines.

InChI:InChI=1/C8H12O3/c1-6(9)11-8-4-2-7(10)3-5-8/h8H,2-5H2,1H3

Upstream product

• 556-48-9 1,4-Cyclohexanediol 
• 108-24-7 acetic anhydride 
• 58512-50-8 (4-hydroxycyclohexyl) acetate 
• 41043-90-7 1,4-diacetoxycyclohexene 
• 13482-22-9 4-hydroxycyclohexanone 
• 4160-49-0 bicyclo[3.1.0]hexan-2-one 
• 622-45-7 cyclohexyl acetate 
• 99183-17-2 4-methoxycyclohexyl acetate 
• 18068-06-9 4-methoxycyclohexan-1-ol 

Downstream Products

• 57438-52-5 4-acetoxy-1-morpholin-4-yl-cyclohexene 
• 101489-33-2 (4-Acetoxy-1-hydroxy-cyclohexyl)-acetic acid ethyl ester 
• 101489-34-3 (4-Acetoxy-1-hydroxy-cyclohexyl)-acetic acid ethyl ester 
• 477344-82-4 acetic acid 4-cyano-4-hydroxy-cyclohexyl ester 
• 477344-82-4 acetic acid 4-cyano-4-hydroxy-cyclohexyl ester 
• 886587-55-9 4-acetoxy-1-[bis(4-hydroxyphenyl)methylene]cyclohexane 
• 886587-59-3 C₁₉H₂₀O₃ 
• 886587-58-2 4-fluoro[bis(4-methoxymethoxyphenyl)methylene]cyclohexane 
• 886587-57-1 4-[bis(4-methoxymethoxyphenyl)methylene]cyclohexanol 
• 886587-56-0 4-acetoxy-1-[bis(4-methoxymethoxyphenyl)methylene]cyclohexane 
• 93675-85-5 rengyol 
• 101489-38-7 trans-1-(2-hydroxyethyl)cyclohexane-1,4-diol 
• 105814-59-3 Acetic acid 2-(4-acetoxy-1-hydroxy-cyclohexyl)-ethyl ester 
• 21048-53-3 methylcyclohex-1-en-4-ol acetate 

Relevant articles and documents

Designing new baeyer-villiger monooxygenases using restricted CASTing

This paper outlines the design and execution of the first mini-evolution of cyclopentanone monooxygenase (CPMO). The methodology described is a relatively inexpensive and rapid way to obtain mutant enzymes with the desired characteristics. Several successful mutants with enhanced enantioselectivities were identified. For example, mutant-catalyzed oxidation of 4- methoxycyclohexanone gave the corresponding lactone with 92% entantiometric excess (ee) compared to the 46% ee achieved with wild-type cyclohexanone monoxygenase (WT-CHMO). The original design of the mini-evolution and the following evaluation of mutants can provide valuable insights into the active site's construction and dynamics and can suggest other catalytically profitable mutations within the putative active site.

Oxidation of Secondary Methyl Ethers to Ketones

We present a mild way of converting secondary methyl ethers into ketones using calcium hypochlorite in aqueous acetonitrile with acetic acid as activator. The reaction is compatible with various oxygen- and nitrogen-containing functional groups and afforded the corresponding ketones in up to 98% yield. The use of this methodology could expand the application of the methyl group as a useful protecting group.

An unexpected oxidation of unactivated methylene C-H using DIB/TBHP protocol

An in situ generated hypervalent iodine species, bis(tert-butylperoxy) iodobenzene, was used as a peroxy radical source for the oxidation of unreactive, remote, and isolated alkyl (cyclic or aliphatic) esters and amides to the corresponding keto compounds under very mild conditions.