41658-69-9Relevant articles and documents
Merrifield resin-supported chain transfer agents, precursors for RAFT polymerization
Takolpuckdee, Pittaya,Mars, Craig A.,Perrier, Sebastien
, p. 3449 - 3452 (2005)
(Chemical Equation Presented) The modification of Merrifield resins to form chain transfer agent (CTA) precursors for reversible addition fragmentation chain transfer (RAFT) polymerization is investigated. A series of CTA precursor resins were prepared an
Gram scale synthesis of alpha-cyanoalkylboronic esters via direct B–B and C–N bond cleavage
Sahoo, Sushree Ranjan,Sarkar, Debayan
supporting information, p. 3308 - 3313 (2020/08/06)
A direct metal-free approach for the synthesis of alpha-cyanoalkylboronic esters from bis-diboron ester and azobis-nitrile compound is reported under ambient temperature and pressure via a free radical procedure.
Radical-triggered three-component coupling reaction of alkenylboronates, α-halocarbonyl compounds, and organolithium reagents: The inverse ylid mechanism
Tappin, Nicholas D. C.,Gn-Gi-lux, Manuel,Renaud, Philippe
supporting information, p. 11498 - 11502 (2018/10/21)
An operationally simple protocol to affect a radical addition to alkenylboronates that spontaneously undergo a [1,2]-metalate shift is described. Overall, the reaction is a three-component coupling of an organolithium, alkenylboronic ester, and halide which takes place with broad scope and good to excellent yields. Experimental mechanistic investigations support the formation of a boron inverse ylid intermediate.