4285-51-2

Basic information

• Product Name: Benzene, (4-pentenylthio)-
• CAS NO: 4285-51-2
• Molecular Formula: C11H14S
• Molecular Weight: 178.298
• Mol File: 4285-51-2.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzene, (4-pentenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (4-pentenylthio)-(4285-51-2)
• EPA Substance Registry System: Benzene, (4-pentenylthio)-(4285-51-2)

Safety Data

• Hazardous Substances Data: 4285-51-2(Hazardous Substances Data)

Upstream product

• 1795-09-1 2-methylthiolane 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 1119-51-3 bromopentene 
• 108-98-5 thiophenol 
• 82239-64-3 pent-1-yn-5-yl phenyl sulfide 
• 74-86-2 acetylene 
• 821-09-0 n-Pent-4-enyl alcohol 
• 3111-52-2 potassium thiophenolate 

Downstream Products

• 144121-60-8 1-phenylhex-5-en-1-ol 
• 182140-48-3 [Pd(Br)(C₆H₅SC₂H₄CHC₂H₄C₆F₅)]2 
• 83705-76-4 5-(phenylthio)-1-iodopentane 
• 57774-95-5 5-(phenylthio)-1-pentanol 
• 41795-36-2 5-(phenylsulfonyl)-1-pentene 

Relevant articles and documents

Synthesis of α-Cyano and α-Sulfonyl Cyclic Ethers via Intramolecular Reactions of Peroxides with Sulfone- And Nitrile-Stabilized Carbanions

The intramolecular reaction of carbon nucleophiles with oxygen-centered electrophiles has been little explored outside of nucleophilic epoxidation. We now report the synthesis of sulfonyl- and cyano-substituted oxacycles via intramolecular reaction of sul

An aryne triggered ring-opening fluorination of cyclic thioethers with potassium fluoride

Herein, we report an aryne triggered ring-opening fluorination protocol of a great variety of saturated sulfur heterocycles. A key factor for the success is the identification of a suitable mediator. Compared to previous methods, this transition-metal free protocol employs low-cost potassium fluoride as the fluorine source. The operational simplicity and mild reaction conditions allow for the rapid synthesis of a wide range of aliphatic fluoride compounds in good yields.

Regioselective Alkoxycarbonylation of Allyl Phenyl Ethers Catalyzed by Pd/dppb under Syngas Conditions

A simple and regioselective synthesis of phenoxy esters and phenylthio esters is reported. The products are obtained by selective alkoxycarbonylation catalyzed by Pd2(dba)3, 1,4-bis(diphenylphisphino)butane (dppb), and syngas (CO/H2) in chloroform/alcohol. This methodology affords bifunctional products in good yield with excellent n-selectivity and without the need to use additives.