82239-64-3

Basic information

• Product Name: Benzene, (4-pentynylthio)-
• CAS NO: 82239-64-3
• Molecular Formula: C11H12S
• Molecular Weight: 176.282
• Mol File: 82239-64-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, (4-pentynylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (4-pentynylthio)-(82239-64-3)
• EPA Substance Registry System: Benzene, (4-pentynylthio)-(82239-64-3)

Safety Data

• Hazardous Substances Data: 82239-64-3(Hazardous Substances Data)

Upstream product

• 4911-65-3 3-chloropropyl phenyl sulfide 
• 1216963-74-4 lithium acetylide-ethylenediamine complex 
• 14267-92-6 1-chloro-4-pentyne 
• 930-69-8 sodium thiophenolate 

Downstream Products

• 4285-51-2 pent-4-en-1-yl phenyl sulfide 
• 1361117-13-6 C₂₂H₂₄S₂ 
• 1284216-36-9 C₁₅H₁₈OS 
• 1284216-37-0 C₁₅H₁₆OS 

Relevant articles and documents

A practical and chemoselective Mo-catalysed sulfoxide reduction protocol using a 3-mercaptopropyl-functionalized silica gel (MPS)

A convenient sulfoxide deoxygenation procedure using a mercaptopropyl-functionalized silica gel as the reducing agent is described. This new protocol based on a heterogeneous reagent displays broad scope and tolerance to reducible functional groups and, from an experimental point of view, enhances previous methods by simplifying the isolation of the sulfide to a simple filtration.

Pinacol as a new green reducing agent: Molybdenum-catalyzed chemoselective reduction of sulfoxides and nitroaromatics

Pinacol is disclosed as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups has been efficiently and selectively reduced with acetone and water being the only by-products of these reactions. Copyright

Tin Radical Addition to Alkynyl Sulfides: Reactivity of the Intermediate Thioalkyl-Substituted β-(Tributylstannyl)vinyl Radicals

Phenyl and benzyl alkynyl sulfides 1a-g and 3a, phenylalkynylamines 19a,b, ethers 22a,b, and selenide 31 reacted with tributyltin radicals to give intermediate β-stannylvinyl radicals, whose fate depended on the nature of the side chain. 4-Phenylthio-substituted but-1-en-2-yl radicals underwent stereospecific 5-exo cyclization on the adjacent phenyl ring.The resulting spirocyclohexadienyl radicals gave thiophenes and thiopyrans by carbon-sulfur bond scission or ring expansion on the exocyclic double bond, respectively.Similar behavior was exhibited by the corresponding selenium-containing radical, which afforded a selenophene almost exclusively. (Benzylthio)alkyl-substituted radicals gave products deriving from intramolecular SH2 substitution at the sulfur atom, whereas propargyl sulfides yielded a stannylallene via a β-scission reaction.No 6(or more)-membered ring closure was observed with pentynyl and hexynyl phenyl sulfides 1b,c, which gave only the (E)-addition products of tin hydride; oxygen- and nitrogen-containing vinyl radicals also gave the (E)-adducts exclusively.An interaction between the unpaired electron orbital and the empty low-energy orbitals of the heteroatom might explain why sulfur and selenium can undergo 5-exo cyclization.