43009-18-3

Basic information

• Product Name: 4-methoxyphenyl dithiocarbamic acid triethylammonium
• Synonyms: 4-methoxyphenyl dithiocarbamic acid triethylammonium
• CAS NO: 43009-18-3
• Molecular Weight: 300.489
• Mol File: 43009-18-3.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: 4-methoxyphenyl dithiocarbamic acid triethylammonium(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxyphenyl dithiocarbamic acid triethylammonium(43009-18-3)
• EPA Substance Registry System: 4-methoxyphenyl dithiocarbamic acid triethylammonium(43009-18-3)

Safety Data

• Hazardous Substances Data: 43009-18-3(Hazardous Substances Data)

Upstream product

• 75-15-0 carbon disulfide 
• 104-94-9 4-methoxy-aniline 
• 121-44-8 triethylamine 

Downstream Products

• 40288-27-5 4-(4-methoxy-phenyl)-5-phenylimino-[1,2,4]dithiazolidine-3-thione 
• 135472-03-6 4-(4-Methoxy-phenyl)-5-[(Z)-4-methoxy-phenylimino]-[1,2,4]dithiazolidine-3-thione 
• 1031-88-5 2-sulfhydryl-3-(4-methoxyphenyl)-quinazolin-4(3H)-one 
• 2293-07-4 1-(4-methoxyphenyl)thiourea 
• 1843-15-8 2-[N-(p-methoxylphenylamino)]-4-phenyl-thiazole 
• 13980-76-2 1-(4-methoxyphenyl)-1H-tetrazole-5-thiol 
• 5350-09-4 3-(4-methoxy-phenyl)-2-thioxo-thiazolidin-4-one 
• 133168-46-4 N-(4-methoxyphenyl)-N’-piperidinethiourea 
• 896854-73-2 C₁₉H₂₂N₂O₃S 
• 431941-85-4 1-(3-Hydroxy-propyl)-3-(4-methoxy-phenyl)-thiourea 
• 61452-16-2 p-anisidino-2 4H dihydro-5,6 thiazine-1,3 
• 193826-40-3 2-((3-(4-methoxyphenyl)-4-oxo-3,4-dihydroquinazoline-2-yl)thio)acetohydrazide 
• 28831-29-0 methyl 2-((3-(4-methoxyphenyl)-4-oxo-3,4-dihydroquinazolin-2-yl)thio)acetate 
• 2284-20-0 4-Methoxyphenyl isothiocyanate 

Relevant articles and documents

T3P - A Benign Desulfurating Reagent in the Synthesis of Isothiocyanates

A number of alkyl, aryl and bifunctional isothiocyanates are obtained in moderate to high yields (41-94%) in a two-step, one-pot reaction of the parent primary amines or their salts with carbon disulfide, followed by reaction of the thus formed dithiocarbamates with T3P (propane phosphonic acid anhydride) as a new and efficient desulfurating agent.

Na2S2O8-mediated efficient synthesis of isothiocyanates from primary amines in water

We have developed two green, practical, and efficient procedures, including a one-pot one, to synthesize isothiocyanates from amines and carbon disulfide via desulfurization with sodium persulfate. Water is used as the solvent. Basic conditions are necessary for good chemoselectivity for isothiocyanates. Structurally diverse linear and branched alkyl amines and aryl amines are readily converted to isothiocyanates by the two procedures in satisfactory yields. Halogens, benzylic C-H bonds, methylthio, nitro, ester, alkenyl, electron-rich or -deficient (hetero)aryls, acetylenyl, and even phenolic and alcoholic hydroxyls are well tolerated. The one-pot procedure in water can also be used to realize the preparation of chiral isothiocyanates from chiral amines, and the modification of bioactive structures with free amino groups. In large-scale preparation, simple and practical purification procedures independent of column chromatography are developed.

Synthesis and supramolecular self-assembly of thioxothiazolidinone derivatives driven by H-bonding and diverse π–hole interactions: A combined experimental and theoretical analysis

Two new 3-aryl-5-(4-nitrobenzylidene)-2-thioxothiazolidin-4-one derivatives (1 & 2) were synthesized by the Knoevenagel condensation reaction of 3-(4-aryl)-2-thioxo-1,3-thiazolidin-4-ones with 4-nitrobenzaldehyde. Both products were isolated as orange cry