436865-51-9

Basic information

• Product Name: Acetamide, N-(3-hydroxy-3-methyl-6-oxo-1,4-cyclohexadien-1-yl)-
• Synonyms: Acetamide, N-(3-hydroxy-3-methyl-6-oxo-1,4-cyclohexadien-1-yl)-
• CAS NO: 436865-51-9
• Molecular Formula: C₉H₁₁NO₃
• Molecular Weight: 0
• Mol File: 436865-51-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Acetamide, N-(3-hydroxy-3-methyl-6-oxo-1,4-cyclohexadien-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-(3-hydroxy-3-methyl-6-oxo-1,4-cyclohexadien-1-yl)-(436865-51-9)
• EPA Substance Registry System: Acetamide, N-(3-hydroxy-3-methyl-6-oxo-1,4-cyclohexadien-1-yl)-(436865-51-9)

Safety Data

• Hazardous Substances Data: 436865-51-9(Hazardous Substances Data)

Upstream product

• 436865-50-8 N-(3-hydroperoxy-3-methyl-6-oxocyclohexa-1,4-dienyl)acetamide 
• 6375-17-3 2-acetylamino-p-cresol 

Relevant articles and documents

An efficient regioselective and diastereoselective synthesis of the epoxy-quinol functionality as building block for the Manumycin antibiotics by the sequence of photooxygenation, reduction and Weitz-Scheffer epoxidation

The photooxygenation of the acetanilide 2 affords the hydroperoxide 3, which by titanium-tetraisopropoxide-catalyzed reduction with dimethyl sulfide gives the corresponding quinol 4. Regioselective and diastereoselective Weitz-Scheffer epoxidation of the latter by tert-butyl hydroperoxide (TBHP) and DBU as base catalyst leads to the cis-epoxy quinol 1, the essential functionality in Manumycin antibiotics.