446262-64-2

Basic information

• Product Name: (4R)-4-benzyl-3-[(2S,4R)-2,4-dimethylhexanoyl]-1,3-oxazolidin-2-one
• Synonyms: (4R)-4-benzyl-3-[(2S,4R)-2,4-dimethylhexanoyl]-1,3-oxazolidin-2-one
• CAS NO: 446262-64-2
• Molecular Weight: 303.401
• Mol File: 446262-64-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4R)-4-benzyl-3-[(2S,4R)-2,4-dimethylhexanoyl]-1,3-oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4R)-4-benzyl-3-[(2S,4R)-2,4-dimethylhexanoyl]-1,3-oxazolidin-2-one(446262-64-2)
• EPA Substance Registry System: (4R)-4-benzyl-3-[(2S,4R)-2,4-dimethylhexanoyl]-1,3-oxazolidin-2-one(446262-64-2)

Safety Data

• Hazardous Substances Data: 446262-64-2(Hazardous Substances Data)

Upstream product

• 221293-02-3 (R)-4-benzyl-3-((R)-4-methylhexanoyl)oxazolidin-2-one 
• 74-88-4 methyl iodide 
• 52745-93-4 (4R)-4-methylhexanoic acid 
• 53353-03-0 (R)-(-)-2,6-dimethyl-2-octene 
• 313653-16-6 methanesulfonic Acid (S)-3,7-dimethyl-oct-6-enyl Ester 
• 7540-51-4 (S)-3,7-dimethyl-6-octen-1-ol 
• 446262-59-5 tert-butyl-dimethyl-(2-methyl-butoxy)-silane 
• 616-16-0 (R)-2-Methyl-1-butanol 
• 101711-78-8 (3R)-3-propionyl-4-benzyloxazolidin-2-one 
• 195305-45-4 (2R)-2-methylbutyl trifluoromethanesulfonate 

Relevant articles and documents

Synthesis of the Entomopathogenic Fungus Metabolites Militarinone C and Fumosorinone A

Militarinone C and fumosorinone A, 3-oligoenoyltetramic acids produced by insect pathogenic fungi, were synthesized for the first time. The pyrrolidine-2,4-dione ring was closed through a late-stage Dieckmann condensation of N-(β-ketoacyl) derivatives of tyrosine, obtained by its acylation with either thioesters or Meldrum's acid derivatives bearing the all-trans-polyene side chain. The latter was built up from (S)-citronellol via an Evans methylation and Wittig or HWE olefinations.