461055-43-6

Basic information

• Product Name: C₈₁H₈₄O₁₂
• Synonyms: C₈₁H₈₄O₁₂
• CAS NO: 461055-43-6
• Molecular Weight: 1249.55
• Mol File: 461055-43-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₈₁H₈₄O₁₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₈₁H₈₄O₁₂(461055-43-6)
• EPA Substance Registry System: C₈₁H₈₄O₁₂(461055-43-6)

Safety Data

• Hazardous Substances Data: 461055-43-6(Hazardous Substances Data)

Upstream product

• 2999-40-8 1,3,5-triacetoxybenzene 
• 461055-42-5 5-bromopentyl-3,5-dibenzyl phloroglucinol 
• 108-73-6 3,5-dihydroxyphenol 
• 111-24-0 1,5-dibromo-pentane 
• 100-51-6 benzyl alcohol 
• 461055-44-7 C₃₉H₄₈O₁₂ 
• 63604-98-8 1,3-dibenzylphloroglucinol 
• 461055-41-4 1,3,5-tris(5-bromopentyloxy)benzene 

Downstream Products

• 1269120-37-7 C₇₄H₇₈O₁₂ 
• 461055-44-7 C₃₉H₄₈O₁₂ 

Relevant articles and documents

Interfacial regions governing internal cavities of dendrimers. Studies of poly(alkyl aryl ether) dendrimers constituted with linkers of varying alkyl chain length

This report deals with a study of the properties of internal cavities of dendritic macromolecules that are capable of encapsulating and mediating photoreactions of guest molecules. The internal cavity structures of dendrimers are determined by the interfacial regions between the aqueous exterior and hydrocarbon like interior constituted by the linkers that connect symmetrically sited branch points constituting the dendrimer and head groups that cap the dendrimers. Phloroglucinol-based poly(alkyl aryl ether) dendrimers constituted with a homologous series of alkyl linkers were undertaken for the current study. Twelve dendrimers within first, second, and third generations, having ethyl, n-propyl, n-butyl, and n-pentyl groups as the linkers and hydroxyl groups at peripheries in each generation, were synthesized. Encapsulation of pyrene and coumarins by aqueous basic solutions of dendrimers were monitored by UV-vis and fluorescence spectroscopies, which showed that a lower generation dendrimer with an optimal alkyl linker presented better encapsulation abilities than a higher generation dendrimer. Norrish type I photoreaction of dibenzyl ketone was carried out within the above series of dendrimers to probe their abilities to hold guests and reactive intermediate radical pairs within themselves. The extent of cage effect from the series of third generation dendrimers was observed to be higher with dendrimers having an n-pentyl group as the linker.

Synthesis of poly(alkyl aryl ether) dendrimers

Poly(alkyl aryl ether) dendrimers of up to four generations composed of a phloroglucinol core, branching components, and pentamethylene spacers are synthesized by a divergent growth methodology. A repetitive synthetic sequence of phenolic O-alkylation and