4612-26-4Relevant articles and documents
Carbazoles compound and organic light-emitting device thereof
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Paragraph 0136-0138, (2019/01/23)
The invention provides a carbazoles compound and an organic light-emitting device thereof, and relates to the technical field of organic photoelectric materials. The carbazoles compound has a specialfused ring structure by connecting substituted or unsubstituted carbazolyl group on a fulvene structure, and the strong photoelectric performance is endowed to the carbazoles compound by a large conjugate Pai electronic system. Since the carbazoles compound is provided with the special rigid plane fused ring structure, the whole movement of the group can be relatively limited, the glass transitiontemperature of the compound is effectively improved, film formation is facilitated. The preparation method of the carbazoles compound is simple, raw materials are easy to obtain, the carbazoles compound as a main body material is applied to an OLED device, the light-emitting efficiency of the device can be obviously improved, the driving voltage of the device can be effectively reduced, and the carbazoles compound is an OLED material with excellent performance.
Exploiting Coupling of Boronic Acids with Triols for a pH-Dependent click-Declick Chemistry
Golovanov, Ivan S.,Mazeina, Galina S.,Nelyubina, Yulia V.,Novikov, Roman A.,Mazur, Anton S.,Britvin, Sergey N.,Tartakovsky, Vladimir A.,Ioffe, Sema L.,Sukhorukov, Alexey Yu.
, p. 9756 - 9773 (2018/09/06)
Click-like condensation of boronic acids with specifically designed triols (boronate-triol coupling) produces stable diamantane adducts in aqueous medium, which can be controllably cleaved to initial components under acidic conditions or by using boric acid as a chemical trigger. This novel click-declick strategy allows for the creation of temporary covalent connections between two or more modular units, which was demonstrated by the synthesis of new fluorophore-labeled natural molecules (peptides, steroids), supramolecular assemblies, modified polymers, boronic acid scavengers, solid-supported organocatalysts, biodegradable COF-like materials, and dynamic combinatorial libraries.
Off-axis digital holographic microscope as described in any one of Claims 1 to 6, includes a light coupled to the target unit (Sa) fluorescence excitation source (17).
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Paragraph 0042; 0043, (2017/01/02)
The invention belongs to the field of medicine synthesis and specifically relates to a preparation method of an anidulafungin side chain intermediate 4'-orthopentyloxy-1,1':4',1'-terphenyl-4-carboxylic acid. The preparation method comprises the following steps: initiating a 1,4-dibromo-benzene material which serves as a starting material to carry out Grignard reagent reaction with magnesium by iodine; then, preparing 1,4-benzene hypoboric acid by virtue of addition and hydrolysis with trimethyl borate; and preparing 4'-orthopentyloxy-1,1':4',1'- terphenyl-ethyl carboxylate by virtue of Suzuki reaction of 1,4-benzene hypoboric acid, 4-pentyloxy bromobenzene and 4-halogenated ethyl benzoate in dioxane-ethanol liquor under catalysis of [1,1'-bis(diphenyl phosphino) ferrocene] palladium dichloride, and then, hydrolyzing to obtain a target product. The preparation method disclosed by the invention can lower process cost, is simple, convenient, safe and reliable to operate, and suitable for industrial production.