4670-62-6

Basic information

• Product Name: TETRABUTYLAMMONIUM THIOPHENOLATE
• Synonyms: THIOPHENOL TETRABUTYLAMMONIUM SALT;TETRABUTYLAMMONIUM THIOPHENOLATE;Tetrabutylammonium thiophenolate technical, >=97.0% (NT)
• CAS NO: 4670-62-6
• Molecular Formula: C₆H₅S*C₁₆H₃₆N
• Molecular Weight: 351.63
• Mol File: 4670-62-6.mol
• Article Data: 4

Chemical Properties

• Melting Point: 77-85 °C
• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: TETRABUTYLAMMONIUM THIOPHENOLATE(CAS DataBase Reference)
• NIST Chemistry Reference: TETRABUTYLAMMONIUM THIOPHENOLATE(4670-62-6)
• EPA Substance Registry System: TETRABUTYLAMMONIUM THIOPHENOLATE(4670-62-6)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• F: 3-10-13
• Hazardous Substances Data: 4670-62-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H36N.C6H6S/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;7-6-4-2-1-3-5-6/h5-16H2,1-4H3;1-5,7H/q+1;/p-1

Upstream product

• 2052-49-5 tetra(n-butyl)ammonium hydroxide 
• 108-98-5 thiophenol 
• 1112-67-0 tetrabutyl-ammonium chloride 
• 930-69-8 sodium thiophenolate 
• 68695-48-7 di-tert-butyl phosphoric acid tetra-n-butylammonium salt 

Downstream Products

• 188290-36-0 thiophene 
• 5780-36-9 2-(methylsulfanyl)thiophene 
• 16718-12-0 2-(Phenylthio)thiophene 
• 139-66-2 diphenyl sulfide 
• 71-43-2 benzene 
• 89883-21-6 2-iodo-3-(perfluorooctyl)norbornane 
• 882-33-7 diphenyldisulfane 
• 69127-72-6 <(tridecafluorohexyl)thio>benzene 
• 20808-07-5 1,2,3,3,3-Pentafluor-1-phenylmercapto-propen-⁽¹⁾ 
• 65799-63-5 Heptafluoroisopropyl phenyl sulfide 
• 127-63-9 diphenyl sulphone 
• 64939-42-0 1-(phenylsulphonyl)-2-(phenylthio)benzene 
• 127299-77-8 Phenyl 3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside 
• 127299-77-8 Phenyl 3,4,6-tri-O-benzyl-1-thio-α-D-glucopyranoside 

Relevant articles and documents

Polymerization of Acrylic Acid Esters initiated by Tetrabutylammonium Alkyl- and Aryl-thiolates

Tetrabutylammonium alkyl- and aryl-thiolates initiate the quantitative polymerization of acrylic acid esters at room temperature to form isotactic polymers having a narrow molecular weight distribution.

Regiospecific reductive elimination from diaryliodonium salts

(Figure Presented) Out-of-plane steric bulk furnished by a cyclophane substituent on iodine(III) strongly destabilizes the transition state in the reductive elimination from diaryliodonium salts and leads to regiochemical control (dubbed SECURE), as is demonstrated by computational and experimental studies. This approach should be general for high-valent maingroup and transition metal ions. X=N3, OAc, PhO, CF3CH2O, SCN, PhS.