65799-63-5

Basic information

• Product Name: Benzene, [[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]thio]-
• CAS NO: 65799-63-5
• Molecular Formula: C9H5F7S
• Molecular Weight: 278.194
• Mol File: 65799-63-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, [[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]thio]-(65799-63-5)
• EPA Substance Registry System: Benzene, [[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]thio]-(65799-63-5)

Safety Data

• Hazardous Substances Data: 65799-63-5(Hazardous Substances Data)

Upstream product

• 5285-87-0 phenyl thiocyanate 
• 2966-54-3 Potassium heptafluorobutyrate 
• 882-33-7 diphenyldisulfane 
• 677-69-0 perfluoroisopropyl iodide 
• 108-98-5 thiophenol 
• 4670-62-6 tetra-N-butylammonium benzenethiolate 
• 930-69-8 sodium thiophenolate 
• 498-66-8 norbornene 
• 116-15-4 perfluoropropylene 

Downstream Products

• 65799-61-3 Phenyl-perfluor-isopropylsulfon 

Relevant articles and documents

Nucleophilic perfluoroalkylation of diaryldisulfides with perfluorocarboxylate salts

A new industrial and economical route to trifluoromethyl aryl sufides by thermal decarboxylation of trifluoroacetate salts has been recently developed. The possibility of generalising this reaction of "trifluorodecarboxylation" to RfCO2K (Rf: CCl3, CF2Cl, CF3CF2, CF3CF2CF2) in order to synthesise RfSAr has been studied. Thus, the reaction was effective with RfCO2K (Rf=CCl3, CF3CF2) and a new route to aryl pentafluoroethyl sufides CF3CF2SAr has been briefly exemplified.

Reaction of Perfluoroalkyl Carbanions with Thiocyanates. Synthesis of Fluorinated Sulfides and Sulfenyl Chlorides

-