4676-99-7

Basic information

• Product Name: 3H-Indol-3-one, 2-phenyl-, oxime
• CAS NO: 4676-99-7
• Molecular Formula: C14H10N2O
• Molecular Weight: 222.246
• Mol File: 4676-99-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 3H-Indol-3-one, 2-phenyl-, oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 3H-Indol-3-one, 2-phenyl-, oxime(4676-99-7)
• EPA Substance Registry System: 3H-Indol-3-one, 2-phenyl-, oxime(4676-99-7)

Safety Data

• Hazardous Substances Data: 4676-99-7(Hazardous Substances Data)

Upstream product

• 2989-63-1 2-phenyl-3H-indol-3-one 
• 948-65-2 2-phenyl-indole 
• 98-86-2 acetophenone 
• 583-11-9 N-(1-phenylethylidene)phenylhydrazine 
• 70-11-1 α-bromoacetophenone 
• 62-53-3 aniline 
• 5883-81-8 2-anilinoacetophenone 
• 64-19-7 acetic acid 
• 67-64-1 acetone 
• 1969-74-0 2-phenylisatogen 
• 31917-92-7 1-oxy-2-phenyl-indol-3-one oxime 
• 302-01-2 hydrazine 
• 7803-49-8 hydroxylamine 
• 64109-88-2 2-phenyl-3-H-indole 

Downstream Products

• 25344-21-2 2-phenyl-indol-3-on-(O-acetyl oxime ) 
• 25344-22-3 2-phenyl-indol-3-one-(O-benzoyl oxime ) 
• 579-93-1 2-(Benzoylamino)benzoic Acid 
• 23041-45-4 3-amino-2-phenylindole 
• 1022-45-3 2-phenyl-4(3H)-quinazolinone 
• 1022-46-4 2-phenyl-4H-3,1-benzoxazin-4-one 
• 40288-69-5 N-(2-cyanophenyl)benzamide 
• 1060712-42-6 (E)-2-phenyl-3H-indol-3-one O-methyl oxime 
• 33738-86-2 N-(2-phenyl-1H-indol-3-yl)acetamide 
• 4771-06-6 2-phenyl-3-nitro-1H-indole 
• 64641-83-4 3-amino-2-phenylindole 
• 6339-33-9 3-imino-2-phenyl-3H-indole 
• 2989-63-1 2-phenyl-3H-indol-3-one 
• 106367-37-7 3-<(1-Oxyl-2,2,5,5-tetramethyl-2,5-dihydropyrrole-3-carbonyloxy)-imino>-2-phenyl-3H-indole 

Relevant articles and documents

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NaNO2/K2S2O8-mediated Selective Radical Nitration/Nitrosation of Indoles: Efficient Approach to 3-Nitro- and 3-Nitrosoindoles

JPZ acknowledges financial support from the National Natural Science Foundation of China (No. 21172163, 21472133), the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), and Key Laboratory of Organic Synthesis of Jiangsu Province (KJS1749). (Figure presented.).

Synthesis of 2-Aminobenzonitriles through Nitrosation Reaction and Sequential Iron(III)-Catalyzed C-C Bond Cleavage of 2-Arylindoles

A variety of 2-aminobenzonitriles were prepared from 2-arylindoles in good to excellent yields through tert-butylnitrite (TBN)-mediated nitrosation and sequential iron(III)-catalyzed C-C Bond cleavage in a one-pot fashion. The 2-aminobenzonitriles can be used to rapidly synthesize benzoxazinones by intramolecular condensation. The present method features an inexpensive iron(III) catalyst, gram scalable preparations, and novel C-C bond cleavage of indoles.