4774-18-9

Basic information

• Product Name: 2-(BENZYLOXY)-6-CHLOROPYRAZINE
• Synonyms: 2-(benzyloxy)-6-chloropyraine;2-chloro-6-(phenylmethoxy)Pyrazine
• CAS NO: 4774-18-9
• Molecular Formula: C₁₁H₉ClN₂O
• Molecular Weight: 220.66
• Mol File: 4774-18-9.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 321.362 °C at 760 mmHg
• Flash Point: 148.155 °C
• Appearance: /
• Density: 1.279 g/cm³
• Vapor Pressure: 0.001mmHg at 25°C
• Refractive Index: 1.593
• CAS DataBase Reference: 2-(BENZYLOXY)-6-CHLOROPYRAZINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(BENZYLOXY)-6-CHLOROPYRAZINE(4774-18-9)
• EPA Substance Registry System: 2-(BENZYLOXY)-6-CHLOROPYRAZINE(4774-18-9)

Safety Data

• Hazardous Substances Data: 4774-18-9(Hazardous Substances Data)

Usage

General Description

2-(Benzyloxy)-6-chloropyrazine is a chemical compound categorized under the group of organohalogens and organonitrogen compounds, specifically a pyrazine. Pyrazines are a class of diazines composed of a six-membered aromatic ring with two nitrogen atoms and has a molecular weight of 212.67 g/mol. Its presence is characterized by its molecular formula C11H9ClN2O. Such chemical compounds usually have a strong odor and occur in a variety of foods and beverages. However, detailed information about the potential uses, properties, production methods, or health effects of this specific compound, 2-(Benzyloxy)-6-chloropyrazine, is currently lacking might involve further research or study.

InChI:InChI=1/C11H9ClN2O/c12-10-6-13-7-11(14-10)15-8-9-4-2-1-3-5-9/h1-7H,8H2

Upstream product

• 4774-14-5 2,6-dichloropyrazine 
• 100-51-6 benzyl alcohol 

Downstream Products

• 181582-01-4 (3R,4R,5R)-3,4-Bis-benzyloxy-2-(3-benzyloxy-5-chloro-pyrazin-2-yl)-5-benzyloxymethyl-tetrahydro-furan-2-ol 
• 181581-96-4 3-Benzyloxy-2-((2S,3S,4R,5R)-3,4-bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl)-5-chloro-pyrazine 
• 1279817-20-7 2-benzyloxy-6-phenylpyrazine 
• 1644057-96-4 C₁₈H₁₆N₂O₂ 
• 1644057-97-5 2-(benzyloxy)-6-(thien-2-yl)pyrazine 
• 1644057-99-7 C₂₃H₃₆N₂OSn 
• 1313033-58-7 2-(benzyloxy)-6-ethylpyrazine 

Relevant articles and documents

Regioselective addition of Grignard reagents to N-acylpyrazinium salts: Synthesis of substituted 1,2-dihydropyrazines and Δ5-2-oxopiperazines

The regioselective addition of Grignard reagents to mono- and disubstituted N-acylpyrazinium salts affording substituted 1,2-dihy-dropyrazines in modest to excellent yields (45–100%) is described. Under acidic conditions, these 1,2-dihydropyrazines can be converted to substituted Δ5-2-oxopiperazines providing a simple and efficient approach towards their preparation.

Synthesis of mono- and diaza-'pyridones' via stille coupling of alkoxystannanes

Various alkoxy-substituted heterocyclic stannanes provide access to the corresponding substituted 'pyridone' moieties via Stille cross-coupling. Both pyridyl and a series of diazinyl stannanes are prepared, and options for unmasking (via demethylation or debenzylation) of the pyridone unit are evaluated. Georg Thieme Verlag Stuttgart. New York.

Alkanesulfonate derivatives and their use as insecticides, acaricides or nematicides

Disclosed herein is a compound of the formula: wherein Ar is pyridine ring, pyridazine ring, pyrimidine ring, pyrazine ring, isoquinoline ring or thiazole ring, and those rings may be substituted by 1?3 of substituents selected from the group consisting of halogen, C1 ?C4 -alkyl, C1 ?C4 -alkoxy, CF3 and nitro, R1 is C1 ?C8 -alkyl; C1 ?C7 -alkyl which is substituted by 1?3 of F, Cl or Br, C1 ?C4 -alkoxy or C1 ?C4 -alkylthio; C3 ?C7 -cycloalkyl which may be substituted by 1?4 of F, Cl or methyl; C3 ?C6 -cycloalkylmethyl which may be substituted by 1?4 of F, Cl, Br or methyl; allyl, propargyl, phenyl or benzyl; R2 is C1 ?C4 -alkyl which may be substituted by 1?3 of F or Cl, x is integer of 0, 1 or 2, excepting wherein Ar is pyridine ring which is substituted by R1 --S(O)x and --O--SO2 R2 at 2- and 6-position and the R1 is C1 ?C7 -alkyl and the pyridine ring is not further substituted or substituted by 1?3 of halogen.