4837-32-5

Basic information

• Product Name: N-(4-methylphenyl)-2-nitro-benzenesulfenamide
• Synonyms: N-(4-methylphenyl)-2-nitro-benzenesulfenamide;4-methyl-N-(2-nitrophenyl)sulfanylaniline
• CAS NO: 4837-32-5
• Molecular Formula: C₁₃H₁₂N₂O₂S
• Molecular Weight: 260.3116
• Mol File: 4837-32-5.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 403°Cat760mmHg
• Flash Point: 197.5°C
• Appearance: /
• Density: 1.3g/cm³
• Vapor Pressure: 1.05E-06mmHg at 25°C
• Refractive Index: 1.66
• CAS DataBase Reference: N-(4-methylphenyl)-2-nitro-benzenesulfenamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-methylphenyl)-2-nitro-benzenesulfenamide(4837-32-5)
• EPA Substance Registry System: N-(4-methylphenyl)-2-nitro-benzenesulfenamide(4837-32-5)

Safety Data

• Hazardous Substances Data: 4837-32-5(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 6, p. 4291, 1965 DOI: 10.1016/S0040-4039(00)71088-4

InChI:InChI=1/C13H12N2O2S/c1-10-6-8-11(9-7-10)14-18-13-5-3-2-4-12(13)15(16)17/h2-9,14H,1H3

Upstream product

• 4837-33-6 o-nitrobenzenesulfenanilide 
• 106-49-0 p-toluidine 
• 7669-54-7 2-nitrobenzenesulfenyl chloride 
• 18512-80-6 benzenethiosulfonic acid S-(2-nitro-phenyl ester) 
• 1155-00-6 bis(2-nitrophenyl)disulfide 
• 88-73-3 2-Chloronitrobenzene 

Downstream Products

• 27332-17-8 4-methyl-2-(2-nitro-phenylsulfanyl)-aniline 
• 92-84-2 10H-phenothiazine 
• 1144-81-6 4-amino-2'-nitrodiphenyl sulphide 
• 1155-00-6 bis(2-nitrophenyl)disulfide 
• 136943-94-7 2'-bromo-4'-methyl-2-nitrobenzensulfenanilide 
• 3939-47-7 3-methyl-10H-phenothiazine 
• 27332-20-3 N-phenyl-2-amino-benzenesulfonamide 
• 19284-81-2 2-(2-nitro)phenylthiophenylamine 

Relevant articles and documents

Organocatalytic Allylic Amination of Morita-Baylis-Hillman Carbonates

An organocatalytic asymmetric allylic amination of Morita-Baylis-Hillman carbonates with aromatic amines in the presence of β-isocupreidine is described. Chiral allylic amines were obtained in almost quantitative yields (90-96%) with moderate enantioselectivity. Recrystallization afforded products in good yields (45-73%) and high optical purity (82-99% ee). This method provides a facile and efficient route to obtain optically active β-lactams, including the building block of the cholesterol-lowering drug Ezetimibe.