4850-72-0

Basic information

• Product Name: Benzene, [(R)-(1,1-dimethylethyl)sulfinyl]-
• CAS NO: 4850-72-0
• Molecular Formula: C10H14OS
• Molecular Weight: 182.287
• Mol File: 4850-72-0.mol
• Article Data: 32

Chemical Properties

• CAS DataBase Reference: Benzene, [(R)-(1,1-dimethylethyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(R)-(1,1-dimethylethyl)sulfinyl]-(4850-72-0)
• EPA Substance Registry System: Benzene, [(R)-(1,1-dimethylethyl)sulfinyl]-(4850-72-0)

Safety Data

• Hazardous Substances Data: 4850-72-0(Hazardous Substances Data)

Upstream product

• 591-51-5 phenyllithium 
• 3019-19-0 tert-butyl phenyl sulfide 
• 591-50-4 iodobenzene 
• 60011-16-7 (_SS)-(+)-tert-butyl tert-butanethiosulfinate 
• 62076-10-2 (tert-butylsulfinyl)benzene 
• 126494-96-0 2-Methyl-propane-2-sulfinic acid (S)-2-hydroxy-1-methyl-2,2-diphenyl-ethyl ester 
• 100-58-3 phenylmagnesium bromide 
• 108-86-1 bromobenzene 
• 67734-35-4 (R)-tert-butyl tert-butanethiosulfinate 
• 623-81-4 diethyl sulphite 
• 623-98-3 dipropyl sulfite 
• 626-85-7 sulfurous acid dibutyl ester 
• 126494-96-0 2,2-diphenyl-1,2-dihydroxypropyl 2-O-tert-butylsulfinate 
• 66967-37-1 2-Methyl-propane-2-sulfinic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 

Downstream Products

• 885130-43-8 (S)-(+)-2,3-dihydro-3-isopropyl-2-(toluene-4-sulfonyl)benzo[d]isothiazole 
• 627503-87-1 N-[(S)-2-methyl-1-phenylpropan-1-yl]-4-methylbenzenesulfonamide 
• 1092722-67-2 (-)-(S)-tert-butyl [(2-diphenylphosphanyl)phenyl] sulfoxide 
• 1242149-01-4 (S)-bis[2-(tert-butylsulfinyl)phenyl] diselenide 
• 1220531-60-1 (R,R)-1,2-bis(tert-butylsulfinyl)benzene 
• 560087-80-1 (S)-ethyl 2-(phenylsulfinyl)acetate 
• 1191465-76-5 (R)-methyl 2-phenyl-2-((S)-phenylsulfinyl)acetate 
• 1310329-84-0 (R)-benzyl (2-(tert-butylsulfinyl)phenyl) sulfane 
• 1310329-85-1 (R)-(2-(tert-butylsulfinyl)phenyl) (naphthalen-1-ylmethyl) sulfane 
• 1310329-86-2 (R)-(2-(tert-butylsulfinyl)phenyl) (2,4,6-trimethylbenzyl) sulfane 
• 1322750-62-8 (R,E)-1-(tert-butylsulfinyl)-2-styrylbenzene 
• 1335243-47-4 C₁₁H₁₄O₂S 

Relevant articles and documents

Chiral Br?nsted-Acid-Catalyzed Asymmetric Oxidation of Sulfenamide by Using H2O2: A Versatile Access to Sulfinamide and Sulfoxide with High Enantioselectivity

Herein, we describe an example of catalytic asymmetric synthesis of sulfinamides. Aromatic sulfenamides were chosen as useful substrates, because of the indispensable N-H bond, which could form an efficient hydrogen bond with chiral phosphoric acid. Hsub

Multivariate Metal-Organic Frameworks as Multifunctional Heterogeneous Asymmetric Catalysts for Sequential Reactions

The search for versatile heterogeneous catalysts with multiple active sites for broad asymmetric transformations has long been of great interest, but it remains a formidable synthetic challenge. Here we demonstrate that multivariate metal-organic frameworks (MTV-MOFs) can be used as an excellent platform to engineer heterogeneous catalysts featuring multiple and cooperative active sites. An isostructural series of 2-fold interpenetrated MTV-MOFs that contain up to three different chiral metallosalen catalysts was constructed and used as efficient and recyclable heterogeneous catalysts for a variety of asymmetric sequential alkene epoxidation/epoxide ring-opening reactions. Interpenetration of the frameworks brings metallosalen units adjacent to each other, allowing cooperative activation, which results in improved efficiency and enantioselectivity over the sum of the individual parts. The fact that manipulation of molecular catalysts in MTV-MOFs can control the activities and selectivities would facilitate the design of novel multifunctional materials for enantioselective processes.

Diastereoconvergent synthesis of trans -5-hydroxy-6-substituted-2- piperidinones by addition-cyclization-deprotection process

A diastereoselective one-pot approach to access trans-5-hydroxy-6- substituted-2-piperidinones by an addition-cyclization-deprotection process has been developed, in which the stereogenic center at the C-6 position was solely controlled by α-OTBS group. The utility of this transformation is demonstrated by the asymmetric synthesis of the enantiomer of (-)-CP-99,994.