62076-10-2

Basic information

• Product Name: Benzene, [(1,1-dimethylethyl)sulfinyl]-, (S)-
• CAS NO: 62076-10-2
• Molecular Formula: C10H14OS
• Molecular Weight: 182.287
• Mol File: 62076-10-2.mol
• Article Data: 73

Chemical Properties

• CAS DataBase Reference: Benzene, [(1,1-dimethylethyl)sulfinyl]-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1,1-dimethylethyl)sulfinyl]-, (S)-(62076-10-2)
• EPA Substance Registry System: Benzene, [(1,1-dimethylethyl)sulfinyl]-, (S)-(62076-10-2)

Safety Data

• Hazardous Substances Data: 62076-10-2(Hazardous Substances Data)

Upstream product

• 3019-19-0 tert-butyl phenyl sulfide 
• 77096-69-6 1-benzenesulfinyl-4-methyl-benzene 
• 594-19-4 tert.-butyl lithium 
• 16491-20-6 (R)-1-methyl-4-(phenylsulfinyl)benzene 
• 100-58-3 phenylmagnesium bromide 
• 7205-94-9 chloromethyl phenyl sulfoxide 
• 100-68-5 methyl-phenyl-thioether 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 108-98-5 thiophenol 
• 75-65-0 tert-butyl alcohol 
• 108-86-1 bromobenzene 
• 31562-40-0 tert-butyl tert-butanethiosulfinate 
• 69857-05-2 propyl benzenesulfinate 
• 677-22-5 tert-butylmagnesium chloride 

Downstream Products

• 142075-24-9 C₁₀H₁₃⁽²⁾HOS 
• 29634-46-6 t-Butyl-o-hydroxyphenylsulfoxid 
• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 1208-20-4 S-phenyl benzenethiosulfinate 
• 882-33-7 diphenyldisulfane 
• 142075-30-7 2-(tert-butylsulfinyl)-N,N-diethylbenzamide 
• 131508-89-9 2-methyl-1-phenylthio-2-trifluoroacetoxypropane 
• 98289-55-5 trans-1-phenylthio-2-trifluoroacetoxycyclohexane 
• 4850-72-0 (S)-(-)-(tert-butylsulfinyl)benzene 
• 4170-71-2 (R)-(tert-butylsulfinyl)benzene 
• 724466-85-7 C₆H₁₀⁽²⁾H₃NO 
• 75-65-0 tert-butyl alcohol 
• 63068-30-4 2-carbomethoxyethenyl phenyl sulfoxide 
• 945-51-7 1,1'-sulfinylbisbenzene 

Relevant articles and documents

Acid-Catalyzed Synthesis of Aryl[4,5]isothiazoles through a Sulfenic Acid Pathway

A new method to efficiently prepare 3-substituted aryl[4,5]isothiazoles by simply heating the starting materials with a catalytic amount of p -toluenesulfonic acid in toluene is reported. This simple procedure is well suitable for a variety of substrates

Thermolysis-Induced Two- or Multicomponent Tandem Reactions Involving Isocyanides and Sulfenic-Acid-Generating Sulfoxides: Access to Diverse Sulfur-Containing Functional Scaffolds

Direct reaction of isocyanides with some sulfenic-acid-generating sulfoxides led to the effective formation of the corresponding thiocarbamic acid S-esters in good to high yields. A multicomponent reaction involving isocyanide, sulfoxide, and a suitable nucleophile has also been developed, providing ready access to a diverse range of sulfur-containing compounds, including isothioureas, carbonimidothioic acid esters, and carboximidothioic acid esters.

Multivariate Metal-Organic Frameworks as Multifunctional Heterogeneous Asymmetric Catalysts for Sequential Reactions

The search for versatile heterogeneous catalysts with multiple active sites for broad asymmetric transformations has long been of great interest, but it remains a formidable synthetic challenge. Here we demonstrate that multivariate metal-organic frameworks (MTV-MOFs) can be used as an excellent platform to engineer heterogeneous catalysts featuring multiple and cooperative active sites. An isostructural series of 2-fold interpenetrated MTV-MOFs that contain up to three different chiral metallosalen catalysts was constructed and used as efficient and recyclable heterogeneous catalysts for a variety of asymmetric sequential alkene epoxidation/epoxide ring-opening reactions. Interpenetration of the frameworks brings metallosalen units adjacent to each other, allowing cooperative activation, which results in improved efficiency and enantioselectivity over the sum of the individual parts. The fact that manipulation of molecular catalysts in MTV-MOFs can control the activities and selectivities would facilitate the design of novel multifunctional materials for enantioselective processes.