4904-55-6

Basic information

• Product Name: Peroxide, bis(cyclohexylcarbonyl)
• CAS NO: 4904-55-6
• Molecular Formula: C14H22O4
• Molecular Weight: 254.326
• Mol File: 4904-55-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Peroxide, bis(cyclohexylcarbonyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Peroxide, bis(cyclohexylcarbonyl)(4904-55-6)
• EPA Substance Registry System: Peroxide, bis(cyclohexylcarbonyl)(4904-55-6)

Safety Data

• Hazardous Substances Data: 4904-55-6(Hazardous Substances Data)

Upstream product

• 98-89-5 Cyclohexanecarboxylic acid 
• 497-19-8 sodium carbonate 
• 2719-27-9 cyclohexanylcarbonyl chloride 
• 22651-87-2 cyclohexanecarboxylic acid anhydride 

Downstream Products

• 4042-30-2 parvaquone 
• 92-51-3 cyclohexylcyclohexane 
• 15840-96-7 cyclohexyl cyclohexanecarboxylate 
• 108-93-0 cyclohexanol 
• 124-38-9 carbon dioxide 
• 542-18-7 cyclohexyl chloride 
• 6372-42-5 cyclohexyldiphenylphosphine 
• 13689-20-8 (cyclohexyl)diphenylphosphane oxide 
• 18869-27-7 (E)-(2-cyclohexylvinyl)benzene 
• 40132-69-2 (Z )-1-(2-cyclohexyl-1-ethenyl)benzene 
• 89482-40-6 2-cyclohexyloxy-1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindole 
• 1678-91-7 ethyl-cyclohexane 
• 2719-26-8 N-phenylcyclohexanamide 
• 42463-29-6 Methyl-phenyl-carbamic acid cyclohexyl ester 

Relevant articles and documents

Alkylation-arylation method and application of olefin compound

The invention discloses an alkyl-arylation method of an olefin compound. The method comprises the following steps: reacting a reaction system comprising a compound a as shown in a formula II, a compound b as shown in a formula III and a compound c as shown in a formula IV to prepare a compound I as shown in a formula I; wherein R1 is selected from one of alkyl, substituted alkyl, heteroaryl and substituted heteroaryl; Ar is selected from one of aryl, substituted aryl, heteroaryl and substituted heteroaryl; R2 is selected from one of alkyl, substituted alkyl, heteroaryl and substituted heteroaryl. The invention further provides application of the method. According to the method provided by the invention, the cheap and easily available catalyst is adopted, the reaction condition is mild, the method is green and environment-friendly, the selectivity and yield of the product are relatively high, a simple and effective method is provided for the field of organic synthesis to obtain the expensive alkyl harmonic diaryl compound, and the method has wide research value and industrial application prospect.

Radical alkylation of C(sp3)-H bonds with diacyl peroxides under catalyst-free conditions

Herein, we describe a protocol for alkylation reactions of C(sp3)-H bonds with diacyl peroxides by means of a process involving cross-coupling between an alkyl radical and an α-Aminoalkyl radical. The mild, catalyst-And additive-free conditions make this protocol superior to previously reported C(sp3)-H alkylation strategies. The protocol was applied to 1,2,3,4-Tetrahydroisoquinolines and a tetrahydro-β-carboline derivative and could be carried out on a gram scale, indicating its utility for the alkylation of late-stage synthetic intermediates.

Copper-Catalyzed Decarboxylative Alkylation of Terminal Alkynes

A copper-catalyzed decarboxylative alkylation of terminal alkynes under mild reaction conditions has been reported. Various alkyl diacyl peroxides were applied as the alkyl source for the formation of C(sp3)?C(sp) bond. A range of terminal alkynes including aryl alkynes and alkyl alkynes delivered the alkylated internal alkynes with good to high performances. Mechanism studies suggested that this reaction involves a free radical pathway. (Figure presented.).