499797-06-7

Basic information

• Product Name: 1,4-Cyclohexadiene-1,2-dicarboxylic acid, 3-[(acetyloxy)methyl]-5-[2-[(2,2-dimethyl-1-oxopropyl)amino]-3-ethoxy-3- oxopropyl]-, dimethyl ester
• CAS NO: 499797-06-7
• Molecular Formula: C23H33NO9
• Molecular Weight: 467.516
• Mol File: 499797-06-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,4-Cyclohexadiene-1,2-dicarboxylic acid, 3-[(acetyloxy)methyl]-5-[2-[(2,2-dimethyl-1-oxopropyl)amino]-3-ethoxy-3- oxopropyl]-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Cyclohexadiene-1,2-dicarboxylic acid, 3-[(acetyloxy)methyl]-5-[2-[(2,2-dimethyl-1-oxopropyl)amino]-3-ethoxy-3- oxopropyl]-, dimethyl ester(499797-06-7)
• EPA Substance Registry System: 1,4-Cyclohexadiene-1,2-dicarboxylic acid, 3-[(acetyloxy)methyl]-5-[2-[(2,2-dimethyl-1-oxopropyl)amino]-3-ethoxy-3- oxopropyl]-, dimethyl ester(499797-06-7)

Safety Data

• Hazardous Substances Data: 499797-06-7(Hazardous Substances Data)

Upstream product

• 290367-39-4 ethyl 2-trimethylacetylamino-4-pentynoate 
• 171922-16-0 ethyl 2-[(diphenylmethylidene)amino]pent-4-ynoate 
• 100860-41-1 ethyl 2-aminopent-4-ynoate 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 290367-43-0 (E/Z)-7-acetoxy-2-(2,2-dimethylpropionylamino)-4-methylenehept-5-enoic acid ethyl ester 

Relevant articles and documents

Synthesis of highly functionalized phenylalanine derivatives via cross-enyne metathesis reactions

A new method for the synthesis of constrained phenylalanine derivatives is described. In this regard, the simple synthesis of acyclic diene building blocks embodying an α-amino acid moiety has been achieved. The diene building blocks have been prepared by cross enyne-metathesis reaction as a key step. The Diels-Alder reaction of the dienes with a dienophile such as dimethyl acetylenedicarboxilate (DMAD) followed by oxidation of the resulting cycloadduct gave highly substituted phenylalanine derivatives.