50366-70-6

Basic information

• Product Name: 3-phenyl-4-tosyl-2-butanone
• Synonyms: 3-phenyl-4-tosyl-2-butanone
• CAS NO: 50366-70-6
• Molecular Weight: 302.394
• Mol File: 50366-70-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-phenyl-4-tosyl-2-butanone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-phenyl-4-tosyl-2-butanone(50366-70-6)
• EPA Substance Registry System: 3-phenyl-4-tosyl-2-butanone(50366-70-6)

Safety Data

• Hazardous Substances Data: 50366-70-6(Hazardous Substances Data)

Upstream product

• 25287-67-6 4-dimethylamino-3-phenyl-butan-2-one; hydrochloride 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 127-66-2 2-Phenyl-3-butyn-2-ol 
• 1584143-93-0 C₁₀H₁₁N₃O 
• 129665-54-9 trans-1-methyl-2-(tosylmethyl)oxirane 
• 129665-71-0 (threo/erythro)-3-phenyl-4-tosyl-2-butanol 

Downstream Products

• 32123-84-5 3-phenylbut-3-en-2-one 

Relevant articles and documents

Reductive radical-initiated 1,2-C migration assisted by an azidyl group

We report here a novel reductive radical-polar crossover reaction that is a reductive radical-initiated 1,2-C migration of 2-azido allyl alcohols enabled by an azidyl group. The reaction tolerates diverse migrating groups, such as alkyl, alkenyl, and aryl groups, allowing access to n+1 ring expansion of small to large rings. The possibility of directly using propargyl alcohols in one-pot is also described. Mechanistic studies indicated that an azidyl group is a good leaving group and provides a driving force for the 1,2-C migration. This journal is

Sulfones via Mannich bases

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