5076-39-1

Basic information

• Product Name: N,N'-Dimethyl-N,N'-diphenylthioharnstoff
• Synonyms: N,N'-Dimethyl-N,N'-diphenylthioharnstoff
• CAS NO: 5076-39-1
• Molecular Weight: 256.371
• Mol File: 5076-39-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N,N'-Dimethyl-N,N'-diphenylthioharnstoff(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-Dimethyl-N,N'-diphenylthioharnstoff(5076-39-1)
• EPA Substance Registry System: N,N'-Dimethyl-N,N'-diphenylthioharnstoff(5076-39-1)

Safety Data

• Hazardous Substances Data: 5076-39-1(Hazardous Substances Data)

Upstream product

• 19009-45-1 N-methyl-N-phenylthiocarbamoyl chloride 
• 100-61-8 N-methylaniline 
• 611-92-7 1,3-dimethyl-1,3-diphenylurea 
• 463-71-8 thiophosgene 
• 552-82-9 benzhydrylidene(methyl)amine 
• 4960-31-0 Tris(methylphenylamino)methan 
• 5080-33-1 bis(trichloromethyl)pentathiodipercarbonate 

Downstream Products

• 611-92-7 1,3-dimethyl-1,3-diphenylurea 
• 1033342-93-6 1-methyl-3,4-diphenylquinolin-2(1H)-one 

Relevant articles and documents

Rhodium-catalyzed direct coupling of benzothioamides with alkenes and alkynes through directed C-H bond cleavage

Rhodium-catalyzed direct coupling of benzothioamides with alkenes proceeds smoothly involving ortho-CH bond cleavage. The thioamides also couple with alkynes under similar conditions accompanied by desulfurization and CN bond cleavage to produce indenone derivatives.

Radical OfC transposition: A metal-free process for conversion of phenols into benzoates and benzamides

We report a metal-free procedure for transformation of phenols into esters and amides of benzoic acids via a new radical cascade. Diaryl thiocarbonates and thiocarbamates, available in a single high-yielding step from phenols, selectively add silyl radicals at the sulfur atom of the CdS moiety. This addition step, analogous to the first step of the Barton-McCombie reaction, produces a carbon radical which undergoes 1,2 OfC transposition through an O-neophyl rearrangement. The usually unfavorable equilibrium in the reversible rearrangement step is shifted forward via a highly exothermic C-S bond scission in the O-centered radical, which furnishes the final benzoic ester or benzamide product. The metal-free preparation of benzoic acid derivatives from phenols provides a potentially useful alternative to metal-catalyzed carbonylation of aryl triflates.

Extremely Reactive C=C Double Bonds, VI. - Tris(methylphenylamino)methane - The Chemistry of Orthoamides

Reactions of the title compound 2 with sulfur, selenium, thiophenol, malononitrile, 1,3-indanedione, fluorenone hydrazone, phenylmagnesium bromide, bromine, thioacetic acid, N,N'-diphenylurea, oxalyl chloride, 9,9-dichloroxanthene, phenyl isocyanate, and stilbene dibromide are described and the mechanisms are discussed.The catalytic influence of 2 on the decomposition of 9-diazofluorene in xylene and mesitylene is discussed.