5111-69-3

Basic information

• Product Name: 5-METHOXYINDAN
• Synonyms: 5-METHOXYINDAN;5-Methoxyindan,97%;5-METHOXYINDAN 97%;5-methoxy-2,3-dihydro-1H-indene;5-methoxyindane
• CAS NO: 5111-69-3
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.2
• Product Categories: Ethers;Organic Building Blocks;Oxygen Compounds
• Mol File: 5111-69-3.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 143-145 °C60 mm Hg(lit.)
• Flash Point: 209 °F
• Appearance: /
• Density: 1.023 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0924mmHg at 25°C
• Refractive Index: n20/D 1.544(lit.)
• CAS DataBase Reference: 5-METHOXYINDAN(CAS DataBase Reference)
• NIST Chemistry Reference: 5-METHOXYINDAN(5111-69-3)
• EPA Substance Registry System: 5-METHOXYINDAN(5111-69-3)

Safety Data

• Safety Statements: S24/25:Avoid contact with skin and eyes.
• WGK Germany: 3
• Hazardous Substances Data: 5111-69-3(Hazardous Substances Data)

Usage

Description

5-METHOXYINDAN is an organic compound with the molecular formula C9H10O. It is a colorless to pale yellow liquid and is used as a chemical intermediate in the synthesis of various compounds.

Uses

Used in Chemical Synthesis:
5-METHOXYINDAN is used as a chemical intermediate for the synthesis of 1,1,2,3?tetrabromo?6?methoxyindene through a photobromination reaction. This reaction allows for the creation of new compounds with potential applications in various industries.
Please note that the provided materials do not mention any specific industries for the use of 5-METHOXYINDAN. The information given is limited to its use as a chemical intermediate in the synthesis of a specific compound. If more information about its applications in different industries is available, it can be included in the response.

InChI:InChI=1/C10H12O/c1-11-10-6-5-8-3-2-4-9(8)7-10/h5-7H,2-4H2,1H3

Upstream product

• 1470-94-6 5-hydroxy-2,3-dihydro-1H-indene 
• 562-54-9 potassium methyl sulfate 
• 77-78-1 dimethyl sulfate 
• 67-56-1 methanol 
• 74-88-4 methyl iodide 
• 496-11-7 INDANE 
• 5111-70-6 5-methoxy-1-indanone 
• 3199-77-7 5-methoxy-2,3-dihydro-1H-inden-1-ol 
• 13623-25-1 6-methoxy-2,3-dihydro-1H-inden-1-one 
• 124688-02-4 6-methoxy-2,3-dihydrospiro[Indene-1,2’-[1,3]dithiolane] 

Downstream Products

• 5111-70-6 5-methoxy-1-indanone 
• 1489-28-7 1,2,3,6,7,7a-hexahydro-5H-inden-5-one 
• 1885-13-8 4-methoxyphthalic acid 
• 73615-83-5 2,3-dihydro-6-methoxy-1H-indene-5-carboxaldehyde 
• 13623-25-1 6-methoxy-2,3-dihydro-1H-inden-1-one 
• 128475-34-3 6,6'-(4-methoxybenzylidene)-bis(5-methoxyindan) 
• 3469-08-7 6-methoxy-1H-indene 
• 438623-78-0 2-carboethoxy-4-methoxy-1,6,7,8-tetrahydrocyclopent[g]indole 
• 438623-83-7 1-benzyl-2-methyl-4-methoxy-1,6,7,8-tetrahydrocyclopent[g]indole 
• 1027036-57-2 1-benzyl-2-methyl-1,6,7,8-tetrahydro-1-aza-as-indacen-4-ol 
• 438623-80-4 2-acetyl-1-benzyl-4-methoxy-1,6,7,8-tetrahydrocyclopent[g]indole 
• 438623-81-5 1-benzyl-2-[2-(1-hydroxyethyl)]-4-methoxy-1,6,7,8-tetrahydrocyclopent[g]indole 
• 438623-92-8 1-(4-fluorobenzyl)-2-methyl-4-methoxy-1,6,7,8-tetrahydrocyclopent[g]indole 
• 847024-73-1 1-benzyl-2-hydroxymethyl-4-methoxy-1,6,7,8-tetrahydrocyclopent[g]indole 

Relevant articles and documents

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Chlorotrimethylsilane and Sodium Iodide: A Remarkable Metal-Free Association for the Desulfurization of Benzylic Dithioketals under Mild Conditions

A novel metal-free process allowing the reductive desulfurization of various benzylic dithioketals to afford diarylmethane and benzylester derivatives with good to excellent yields is reported. At room temperature, this mild reduction process requires only the use of TMSCl and NaI in CH2Cl2 and tolerates a large variety of functional groups. (Figure presented.).

Efficient palladium-catalyzed C-O hydrogenolysis of benzylic alcohols and aromatic ketones with polymethylhydrosiloxane

A simple method has been developed for the reductive deoxygenation of aromatic ketones and benzylic alcohols in the presence of polymethylhydrosiloxane (PMHS). The reductive deoxygenation of aromatic ketones and benzylic alcohols, including secondary alcohols, to the corresponding methylene hydrocarbons has been achieved in good to excellent yields using palladium chloride (PdCl2) as catalyst and PMHS as hydride source. Such deoxygenations were successfully with aryl alkyl ketones and diaryl ketones, as exemplified by the reductive deoxygenation of acetophenone and benzopheneone, respectively. The corresponding benzylic alcohols and secondary alcohol analogues could also be converted into their respective methylene hydrocarbons by the PdCl2/PMHS system.