51223-59-7Relevant articles and documents
Fe-Catalyzed Amination of (Hetero)Arenes with a Redox-Active Aminating Reagent under Mild Conditions
Liu, Jianzhong,Wu, Kai,Shen, Tao,Liang, Yujie,Zou, Miancheng,Zhu, Yuchao,Li, Xinwei,Li, Xinyao,Jiao, Ning
supporting information, p. 563 - 567 (2017/01/18)
A novel and efficient Fe-catalyzed direct C?H amination (NH2) of arenes is reported using a new redox-active aminating reagent. The reaction is simple, and can be performed under air, mild, and redox-neutral conditions. This protocol has a broad substrate scope and could be used in the late-stage modification of bioactive compounds. Mechanistic studies demonstrate that a radical pathway could be involved in this transformation.
SYNTHESIS AND PESTICIDAL ACTIVITY OF N,N'-DIACYL DERIVATIVES OF 4-CHLORO-1,2-PHENYLENDIAMINE
Molchanov, L. V.,Ayupova, A. T.,Kadyrov, Ch. Sh.,Shapkin, V. A.
, p. 196 - 198 (2007/10/02)
The acylation of 2-aminoacyl-chloroanilines with acid anhydrides has given N,N'-diacyl derivatives of 4-chloro-1,2-phenylenediamine.Their fungicidal activities have been investigated.It has been shown that in cotton plants they are converted into 2-alkyl-5-chlorobenzimidazoles.